MH or MH2→MOH or M(OH)2+H2MH or MH2→MOH or M(OH)2+H2 ionic hydrides with group 1 and Ca, Sr, and Ba H2+C→(no reaction)H2+C→(no reaction) 3H2+N2→2NH33H2+N2→2NH3 requires high pressure and temperature; low yield 2H2+O2→2H2O2H2+O2→2H2O exother...
After reduction in H2 at elevated temperature, sodium compounds including NaOH molten salt are formed in the NNFM anode, which diffuses into the GDC electrolyte, creating a composite electrolyte of “GDC-sodium compounds” with high ionic conductivity. The ionic conductivity of the “GDC-sodium ...
biomedicine, device, sensing, and printing arenas. However, covalent organic frameworks are generally not dispersible in common solvents resulting in the poor processability, which severely obstruct their application in practice. In this study, we develop a convenient top-down process for fabricating sol...
A distance criterion (H···I < 3 Å) appears to have been used to determine whether or not a hydrogen bonding interaction is present in o-CH3NH3PbI325. However, what other criteria were used to identify and characterize such interactions in the crystallographic studies is unclear. ...
A convenient laboratory preparation involves the reduction of bromine or iodine with red phosphorus and water: (22)2P+6H2O+3X2X=BrorI→6HX+2H3PO3 (23)H3PO3+H2O+X2→2HX+H3PO4 A reaction analogous to Eq. (18) may be employed if the acid is nonoxidizing (e.g., H3PO4), and sodiu...
Iodo-transformations using the reagent system I2/H2O2 were studied in the water miscible ionic liquid (IL) 1-butyl-3-methyl imidazolium tetrafluoroborate (bmimBF4) and in water immiscible IL, 1-butyl-3-methyl imidazolium hexafluorophosphate (bmimPF6). Two different forms of H2O2 as mediators of ...
vastly exceeding that expected for a standard viscous system. Hydrogen and iodine form an ionic plasma within CSF of the human brain. The choroid plexus of the human brain is designed to add iodine to CSF. CSF, you will recall is an ultra-filtrate of blood plasma and is made up of 99.9...
1 | Design scheme of solution-processable covalent organic frameworks (COFs). a Illustration of fabricating solution-processable COFs. The dash line represents π-π interactions and/or C‒H···π interactions. VOC represents volatile organic compound, ILs represents ionic liquids; b Structure of...
Water electrolysis is a sustainable approach for hydrogen production by using electricity from clean energy sources. However, both the hydrogen evolution r
Selective inter- and intramolecular oxidations with α-silyloxyalkyl hydroperoxides have been reviewed.373 There has been some controversy over whether TMS perchlorate is covalent374 or in equilibrium between covalent and ionic forms.375 View chapter Reference work 1995, Comprehensive Organometallic Chemistr...