Hydrogen Abstraction Reactions by NH2(X2B1)‐Radicals from Hydrocarbons in the Gas Phase 喜欢 0 阅读量: 15 作者:W Hack,H Kurzke,P Rouveirolles,HG Wagner 摘要: The NH2(2B1) radical reactions with saturated hydrocarbons, toluene and acetaldehyde were investigated in an isothermal discharge flow...
Mosseri S., Alfassi Z. B. and Neta P. Absolute rate con- stants for hydrogen abstraction from hydrocarbons by the trichloromethylperoxy radical. Int. J. Chem. Kinet. 19 (1987), 309-17.Mosseri S, Alfassi ZB, Neta P (1987) Int J Chem Kinet 19:309. : 10.1002/kin.550190405...
Hydrogen abstraction from unactivated hydrocarbons using a photochemically excited isoindoline nitroxide - Bottle, Chand, et al. - 1997Bottle, S.E.; Chand, U.; Micallef, A.S. Hydrogen abstraction from unactivated hydrocarbons using a photochemically excited isoindoline nitroxide. Chem. Lett. 1997, ...
Six polycyclic aliphatic hydrocarbons were allowed to react with the trichloromethyl radical photolytically generated from bromotrichloromethane at 40°. Relative rates of hydrogenion were correlated with a computer analysis of the change in strain energy in going from the ground state to the intermedia...
Density functional theory kinetic assessment of hydrogen abstraction from hydrocarbons by O2. MARROUNI K E,ABOU-RACHID H,KALIAGUINE S. Journal of Molecular Structure . 2004MARROUNI K E,ABOU-RACHID H,KALIAGUINE S.Density functional theory kinetic assessment of hydrogen abstraction from hydrocarbons by...
The photochemically excited nitroxide, 1,1,3,3-tetramethylisoindolin-2-yloxyl (1*), abstracts primary, secondary or tertiary hydrogens from unactivated hydrocarbons including cyclohexane, isobutane and n-butane. The resultant carbon-centred radicals are rapidly and efficiently trapped by ground state ...
Saturated hydrocarbon radicals in the hybrid orbital all-valence-electron basis possess a nonbonding molecular orbital whose eigencoefficients can be written by inspection. Perturbational MO calculations using these coefficients lead to good correlations of hydrogen abstraction reactivity data....
Hydrogen abstraction reaction from polycyclic aromatic hydrocarbons (PAHs) is an important reaction class for PAHs consumption and soot formation. In this work, the reaction kinetics for a series of PAHs containing up to seven aromatic rings by vinyl radical are systematically investigated using the M...
doi:10.1002/chin.198731092MOSSERI, S.ALFASSI, Z. B.NETA, P.ChemInformMosseri S., Alfassi Z. B. and Neta P. Absolute rate con- stants for hydrogen abstraction from hydrocarbons by the trichloromethylperoxy radical. Int. J. Chem. Kinet. 19 (1987), 309-17....
Chem.P.Chem.NETAChem.WileyCheminformMosseri, S., Z. B. Alfassi, and P. Neta. 1987 . Absolute rate constants for hydrogen abstraction from hydrocarbons by the trichloromethylperoxy radical. Int. J. Chem. Kinet 19: 309 – 317 .Mosseri S., Alfassi Z. B. and Neta P. Absolute rate ...