烯烃的硼氢化-氧化反应Hydroboration-OxidationofAlkenes 下载积分: 1500 内容提示: 中国药科大学 China Pharmaceutical University 烯烃的硼氢化-氧化反应 Hydroboration-Oxidation of Alkenes 周萍 副教授 精业济群 文档格式:PPT | 页数:19 | 浏览次数:503 | 上传日期:2018-07-16 10:31:15 | 文档星级: 中国...
中国药科大学ChinaPharmaceuticalUniversity烯烃的硼氢化-氧化反应Hydroboration-OxidationofAlkenes周萍副教授精业济群TheNobelPrizeinChemistry1979HerbertC.Brown1912~2004GeorgWittig1897~1987"fortheirdevelopmentoftheuseofboron-andphosphorus-containingcompounds,respectively,intoimportantreagentsinorganicsynthesis"一、发现硼氢化...
烯烃的硼氢化-氧化反应 Hydroboration-OxidationofAlkenes 周萍 中国药科大学 ChinaPharmaceuticalUniversity 副教授 精业济群 一、发现 TheNobelPrizeinChemistry1979 HerbertC.BrownGeorgWittig1912~20041897~1987"fortheirdevelopmentoftheuseofboron-andphosphorus-containingcompounds,respectively,intoimportantreagentsinorganic...
1、中国药科大学中国药科大学China Pharmaceutical University 烯烃的硼氢化-氧化反应Hydroboration-Oxidation of Alkenes周萍周萍 副教授副教授精业济群精业济群The Nobel Prize in Chemistry 1979 Herbert C. Brown 19122004Georg Wittig18971987for their development of the use of boron- and phosphorus-containing comp...
烯烃的硼氢化-氧化反应 Hydroboration-Oxidation of Alkenes周萍副教授精业济群The Nobel Prize in Chemistry 1979Herbert C. Brown 1912~2004 Wittig1897~1987"for their development of the use of boron- and phosph
Asymmetric hydroboration-oxidation of alkenes by means of deuterium or tritium labelled asymmetric monoalkylboranesTritiated MonoalkylboraneDeuterated MonoalkylboraneAsymmetric Synthesis(2-(1,3-dithianyl))myrtanylborane (MDBH2)Chiral Labelled Alcohol...
oxidationAn efficient flow process for the selective hydroboration and oxidation of different alkenes using 9〣BN allows facile conversion in high productivity (1.4 g/h) of amorpha11ヾiene to the corresponding alcohol, which is an advanced intermediate in the synthesis of the antimalarial drug ...
Alkenes: Hydroboration‐Oxidation Water can be added to an alkene in such a way that the major product is not that predicted by the Markovnikov rule. An example of such a reaction is the indirect addition of water to an alkene via ahydroboration‐oxidation reaction.In this reaction, a disubst...
dilute acid. Selection of acid is important . Conjugate base of the acid should not interfere in the reaction. There are other means by which alkenes can be converted to alcohols. Oxymercuration demercuration gives Markovnikoff's alcohols while hydroboration oxidation give Anti Markovnikoff's ...
Hydroboration of unsaturated compounds such like alkenes or alkynes is one of the most powerful and straightforward methodology to access various organoboranes which have found widespread application in oxidation, amination and coupling reaction.1 Compared with hydroboration of non-polarized multiple bonds,...