Paired electrocatalysis unlocks cross-dehydrogenative coupling of C(sp3)-H bonds using a pentacoordinated cobalt-salen catalyst Cross-dehydrogenative coupling (CDC) of C-H bonds is an ideal approach for C-C bond construction but suffers from low selectivity of similar C-H bonds. Here, the autho...
Homogeneous catalysis is a type of catalysis in which the catalyst operates in the same phase as the reactants — usually dissolved in a solvent. Mechanistic studies of homogeneous catalysts are generally easier than those of heterogeneous catalysts, which aids optimization. They can, however, be ...
Other important properties of the catalyst are its stability and the ease by which it can be recovered for reuse from the product, starting material and solvent mixture. The number of catalytic reactions is huge and in an introduction like this they cannot even be mentioned in a table or ...
During the last two decades, the chemistry of organoactinides has flourished, reaching a high level of sophistication. The use of organoactinide complexes as stoichiometric or catalytic compounds to promote synthetically important organic transformations has matured due to their rich, complex, and unique...
oxygen-containing organiccompounds. Acobaltcarbonyl catalyst Co2(CO)8is employed; this hydrocarbon-soluble catalyst is believed to activate hydrogen by formation of HCo(CO)4, which then reacts with the olefin. This reaction has led to a number of studies of organometallicchemistry.Copper,silver, ...
We evaluated a new liquid homogeneous assay for the direct measurement of high density lipoprotein cholesterol (HDL-C Plus) in seven laboratories. The assa... M Nauck,MS Graziani,J Jarausch,... - 《Clinical Chemistry & Laboratory Medicine》 被引量: 18发表: 1999年 加载更多0...
PG Jessop,F Joó,CC Tai - 《Coordination Chemistry Reviews》 被引量: 626发表: 2004年 Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium-Phosphine Catalyst (2012). Hydrogenation of carbon dioxide to methanol by using a homogeneous ruthenium–phosphine catalyst . Angew. Chem...
The turnover frequency (TOF) of the reaction was as high as 9.5 h−1, which is comparable with the best level of the FTS reaction using the Ru0 catalyst. Moreover, the products were all n-paraffins, which has not been reported before in liquid fuel synthesis via CO2 hydrogenation. As...
can be selectively accessed by fine tuning of reaction conditions. This review describes the most recent advances in the area of amide hydrogenation using H2exclusively and molecularly defined homogeneous as well as nano-structured heterogeneous catalysts, with a special focus on catalyst development and...
We investigate the photocatalytic performance of the spiral nanosheets, finding emergent chemical functionality in the MSLs. Bulk BiOCl (Supplementary Fig.16) is explored for comparison. The photocatalytic degradation of Rhodamine B with BiOCl as the catalyst is chosen for this purpose. The results ar...