Hofmann-typeIt is of great significance to capture radioiodine from nuclear-related activities. Herein, We fabricated two kinds of hybrid aerogels composed with bimetal Hofmann-type metal-organic frameworks (Co鈥揊e)II(pz)[NiII(CN)4] and cellulose aerogels by in-situ growth and doping method (...
Metal–organic frameworksSpin-crossover·G·HO} (; dpa=1,2-di(4-pyridyl)ethane, G=dpa, bibenzyl (bbz) and stilbene (stb)) have been prepared by using a long and flexible ligand dpa. These compounds formed analogous 3-D elongated Hofmann-type frameworks based on 2-D planar layers ...
Metal-organic frameworksBimetalOxygen evolution reactionThe development of efficient oxygen evolution reaction (OER) catalyst is the key to solve the slow reaction kinetics and is of great significance for the conversion and storage of renewable energy. In this paper, bimetallic/carbon nanosheets ...
Metal-organic frameworksThin filmsNanoparticlesNanomaterialsHofmann-type clathratesMetal鈥搊rganic frameworks (MOFs) have been of particular interest to researchers because of their structural designability, robustness, and rich science arising from uniform porosity. Among them, Hofmann-type MOFs, which are...
The results suggested that this metal-organic framework@cellulose hybrid aerogel showed great potential in iodine treatment and could be applied in a wide field.doi:10.1016/j.micromeso.2020.110386Yuhang WuYuanbo XieFangyuan ZhongJunkuo GaoJuming Yao...
Metal-organic frameworksThe incorporation of spin-crossover (SCO) properties into metal-organic frameworks (MOFs) is an appealing subclass of multifunctional MOFs with potential applications in molecular sensing. This review focuses on the design of SCO Hofmann-type MOFs, with emphasis on the guest ...
Sciortino NF, Scherl-Gruenwald KR, Chastanet G, Halder GJ, Chapman KW, Letard J-F, Kepert CJ, Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework, Angew. Chem. Int. Ed., Engl. (2012) 51, 10154-10158....
The series of Hofmann-type solids studied in this work are also appropriate building blocks for the formation of hybrid inorganic–organic materials, replacing the ammonia and water molecules coordinated to the axial positions of the octahedral metal by organic molecules [11,16]. When molecules with...
Inside Cover: Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework (Angew. Chem. Int. Ed. 40/2012)Hofmann frameworkmetal–organic frameworksmolecular electronicsphotophysicsspin crossover...
Hofmann-typeThe change of fluorescence emission manipulated by spin state transition attracts considerable attention owing to its potential applications in magneto-optical switching devices. Herein, we report two two-dimensional (2D) Hofmann-type spin crossover (SCO) metal-organic frameworks (MOFs) [...