Hofmann-type coordination polymersPhosphidationNi2P nanoplatesElectrocatalystsInsulin oxidationIt is of key importance to design efficient insulin electrocatalysts based on nonprecious noble metal-free. However, the design of advanced nanostructured based metal phosphides is scarcely reported. In this work, ...
Porous coordination polymersMetal–organic frameworksSpin-crossover·G·HO} (; dpa=1,2-di(4-pyridyl)ethane, G=dpa, bibenzyl (bbz) and stilbene (stb)) have been prepared by using a long and flexible ligand dpa. These compounds formed analogous 3-D elongated Hofmann-type frameworks based on...
The reaction of ferrous salts and square‐planar tetracyanometallates [M II (CN) 4 ] 2 (M=Pd, Pt) with ligand 4‐(1H‐pyrazol‐3‐yl)pyridine (Hppy) resulted in the formation of two two‐dimensional (2D) Hofmann‐like coordination polymers (CPs) with the general formula of {Fe II ...
Coordination polymersTrimethyltin chlorideCrystal structuresAqueous solutions of K 2[Ni(CN) 4] readily absorb Me 3SnCl from the vapour phase to afford, at a temperature of 4°C, well-grown single crystals of [(Me 3Sn) 2Ni(CN) 4], 1. In contrast to the recently reported quasi-homologue...
The reaction of ferrous salts and square planar tetracyanometallates [MII(CN)4]2- (M = Pd, Pt) with ligand 4-(1H-pyrazol-3-yl)pyridine (Hppy) resulted in the formation of two two-dimensional (2D) Hofmann-like coordination polymers (CPs) with general formula of {FeII(Hppy)2[MII(...
We report herein the synthesis and characterization of two unprecedented isomorphous spin-crossover two-dimensional coordination polymers of the Hofmann-type formulated {FeII(Hdpyan)2(μ2-[MII(CN)4])2}, with MII = Pd, Pt and Hdpyan is the in situ partially protonated form of 2,5-(di...
Hofmann-typeironpolymersspin-crossovertwo-stepAn unprecedented two-step spin-crossover behavior with the sequence of γ_(HS)=1γ_(HS)=3/4?γ_(HS)=1/4 was observed in two-dimensional Hofmann type coordination polymer [Fe(isoq)_2{Ag(CN)_2}_2] (isoq=isoquinoline), which resulted from...
Three porous coordination polymers {Fe(dpa)[Pt(CN)4]·G·nH2O} (1-G; dpa = 1,2-di(4-pyridyl)ethane, G = dpa, bibenzyl (bbz) and stilbene (stb)) have been prepared by using a long and flexible ligand dpa. These compounds formed analogous 3-D elongated Hofmann-type ...
Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methodsTwo new 2-dimensional cyanide-bridged coordination polymers [Zn(H$_{2}$O)$_{2}$Ni(CN)$_{4}$ 6(H$_{2}$O) and ...
ammonia - aniline - coordination polymers - inclusion compounds - IR spectra - tetracyanometallateInfrared spectra of Mn(NH3)2M(CN)4·2C6H5NH2 (M = Zn, Cd or Hg) are reported. The spectral data suggest that these compounds are similar in structure to Hofmann-Td-type clathrates....