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A high-yield, high-purity synthesis of (ReO_3F)_∞ has been achieved by solvolysis of Re_2O_7 in anhydrous HF (aHF) followed by reaction of the water formed with dissolved F_2 at room temperature. The improved synthesis has allowed the Lewis acid and fluoride ion acceptor properties of...
The calculated distance and bisector angle &thgr; are in reasonable agreement with experiment; the calculated binding energy can be used to provide a good estimate of the (as yet unknown) experimental value. Morokuma component analyses and simple electrostatic (molecular mechanics) calculations have ...
The structure of (4-ClC5H4N)4Pd(C5HF6O2)2 Palladium bis(hexafluoroacetylacetonate), Pd(F6acac)2, reacts with a wide variety of Lewis bases to form 4:1 adducts of the type (L4Pd2)(F6acac)2 where L i... AR Siedle,LH Pignolet - 《Inorganic Chemistry》 被引量: 0发表: 1982年 ...
Carbonyl and nitrosyl diruthenium compounds: Crystal structure of Ru-2(O2CMe)(DPhF)(3)(CO) BF4 center dot CH2Cl2 and its isomorphous nitrosyl analogueBarral, M CarmenHerrero, SantiagoJimenezAparicio, ReyesTorres, M RosarioUrbanos, Francisco A...
molecules Article Highly Efficient Synthesis of Substituted 3,4-Dihydropyrimidin-2-(1H)-ones (DHPMs) Catalyzed by Hf(OTf)4: Mechanistic Insights into Reaction Pathways under Metal Lewis Acid Catalysis and Solvent-Free Conditions Rui Kong, Shuai-Bo Han, Jing-Ying Wei, Xiao-Chong Peng, Zhen-...
lewis-tunstall-interview.md long-range-transformers.md lora.md mask2former.md meg-mitchell-interview.md megatron-training.md ml-director-insights-2.md ml-director-insights-3.md ml-director-insights-4.md ml-director-insights.md ml-for-games-1.md ml-for-games-2.md ml-for-g...
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Crystal structureChemical synthesisMagnetic measurementsSingle crystals of Gd(HF_2CCOO)_3(H_2O)_2 centre dot H_2O have been obtained by reaction of Gd_2O_3 with HF_2CCOOH in water. Data collection was earned out using a STOE imaging plate diffractometer at 173 K. The compound ...