Microwave and quantum chemical study of propargyl selenocyanate (HC[triple bond]CCH2SeC[triple bond]N).doi:10.1021/jp810810fHarald MllendalAlexey KonovalovJean-Claude GuilleminJ Phys Chem A
- InHC≡C-COOH, the alpha carbon (the one directly attached to the -COOH group) issp hybridizeddue to the triple bond. - InH2C=CH-COOH, the alpha carbon issp² hybridizeddue to the double bond. - InCH3-CH2-COOH, the alpha carbon issp³ hybridizedas it is connected to single bo...
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The Nature of the Chemical Bond Revisited: An Energy‐Partitioning Analysis of Nonpolar Bonds The orbital term Delta E(orb) (72.4 %) makes an even greater contribution to the HC triple bond CH triple bond. The contribution of Delta E(orb) ... A Kovács,C Esterhuysen,G Frenking - 《Chem...
Infrared and DFT investigations of the XC[triple bond]ReX3 and HC[triple bond]ReX3 complexes: Jahn-Teller distortion and the methylidyne C-X(H) stretching ... Infrared and DFT investigations of the XC[triple bond]ReX3 and HC[triple bond]ReX3 complexes: Jahn-Teller distortion and the meth...
The other major by-product was the aldehyde 9 formed by the attack on the carbon 2 of double bond(2)(3) The selective functionalization of alkyl alkenes towards aldehydes is also an important goal for industry. Therefore, we were also interested in the hydroformylation of terminal and internal...
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Cooperative metal-boron interactions in the reaction of nido-l,2-(Cp*RuH)2B3H7,Cp* = eta5-C5Me5,with HC(triple bond)CPh[J].Journal of the American Chemical Society,2005.4831-4844.Hong Yan;Bruce C.Noll;Thomas P.Fehlner.Cooperative Metal-Boron Interactions in the Reaction of nido-1,...