When trying to make alkanes reactive, we must first perform aradical halogenationto add a halogen and allow for further reactions to take place. The oneexceptionwe must remember is that when doing a radical chl
03 Alkanes and Nomenclature 04 Conformations and Cycloalkanes 05 A Primer On Organic Reactions 06 Free Radical Reactions 07 Stereochemistry and Chirality 08 Substitution Reactions 09 Elimination Reactions 10 Rearrangements 11 SN1/SN2/E1/E2 Decision 12 Alkene Reactions 13 Alkyne Reactions ...
A wide range of geminal diiodoalkanes and bromo(iodo)alkanes (>40 examples) are directly prepared from various trisubstituted alkenes, including both cyclic and acyclic olefins. This C=C cleavage is highly chemoselective and produces geminal dihalide ketones in good yields. Mechanistic investigations ...
Halogenation is one of the most effective means to introduce functionality in saturated or unsaturated hydrocarbons. The relatively low reactivity of alkanes and alkenes requires reactive reagents for substitution. A large number of well-established methods for the interconversion of organic halides to oth...
1. A Review of General Chemistry5h 5m 2. Molecular Representations1h 14m 3. Acids and Bases2h 46m 4. Alkanes and Cycloalkanes4h 19m 5. Chirality3h 39m 6. Thermodynamics and Kinetics1h 22m 7. Substitution Reactions1h 48m 8. Elimination Reactions2h 30m 9. Alkenes and Alkynes2h 9m 10. Ad...
to produce densely functionalized molecular scaffolds is highly attractive but challenging. Here we report an efficient photo-mediated deconstructive germinal dihalogenation of carbon-carbon double bonds. A wide range of geminal diiodoalkanes and bromo(iodo)alkanes (>40 examples) are directly prepared fro...
New versatile biomimetic reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons J. Am. Chem. Soc., 105 (1983), pp. 3101-3110 CrossrefView in ScopusGoogle Scholar Petrone et al., 2016 D.A. Petrone, J. Ye, M. Lautens Modern transition-metal-catalyzed ...
New versatile biomimetic reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons. J Am Chem Soc 105(10):3101–3110 Google Scholar Velusamy S, Punniyamurthy T (2004) Novel vanadium-catalyzed oxidation of alcohols to aldehydes and ketones under atmospheric oxygen. ...
In the oxyhalogenation of alkanes, it is advantageous to control the relative amounts of reactant gases to minimize formation of polyhalogenated alkanes, such as methylene chloride (CH2Cl2), chloroform, dihalo ethanes, etc. This may be achieved in a continuous process by regulating the flow of...
WO/2001/038275 May, 2001 DEHYDROHALOGENATION OF HALOGENATED ALKANES USING RARE EARTH HALIDE OR OXYHALIDE CATALYST WO/2001/042176 June, 2001 PROCESS FOR VINYL CHLORIDE MANUFACTURE FROM ETHANE AND ETHYLENE WITH IMMEDIATE HC1 RECOVERY FROM REACTOR EFFLUENT WO/2002/094749 November, 2002 PRODUCTION OF VINYL...