Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1, 2- dichalcogenolate carborane ligands, Chin[J].Science Bulltin,2003,(16):1733-1736.Kong, Q,Jin, G.-X,Cai, S,Weng, L.Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1,2-dic...
The reaction of RuCl(3)(solv.)(n) with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.DOI...
The good SIB performance of the MoSe2/MCFs@NC electrode is verified by theoretical simulation and reaction kinetics analysis. EXPERIMENTAL SECTION Synthesis of MCFs Polyacrylonitrile (PAN, 0.4 g) and polystyrene (PS, 0.4 g) were dissolved in 5 mL of N,N-dimethylformamide at 60°C ...
Examines the synthesis and reaction of 16-electron Cp[supt]Rh halfsandwich complexes containing 1,2-dichalcogenolate carborane ligands. Difference in the nature of function between the two halfsandwiches; Schematic diagram for the synthesis and reactions of 16-electron complexes; Table showing the ...
科学通报(英文版)doi:10.1360/02wb0215KONG Qingan, JIN Guoxin, CAI Shuyi & WENG Linhong Laboratory of Molecular Catalysis and Innovative Material, Chemistry Department, Fudan University, Shanghai 200433, China Correspondence should be addressed to Jin Guoxin (e-mail: gxjin@ fudan.edu.cn)...
attempts of the synthesis of highly functionalized porphyrins at the β -positions: nitration of exhaustively substituted moieties in the eastern half and mass -spectral study of the reaction products 来自 dx.doi.org 喜欢 0 阅读量: 1 作者:...
Zr(C5H5)(6,6-dmch)(PMe3)2, an edge-bridged half-open zirconocene—synthesis, structure, and its reaction with C6H5C2SiMe3.Alkyne complexesHalf-open zirconocenesPentadienyl complexesThe synthesis and characterization of an edge-bridged half-open zirconocene, Zr(C5H5)(dmch)(PMe3)2 (dmch=...
Coupling reactionZirconium complexThe synthesis and characterization of the new, 16 electron half-open zirconocenes, Zr(C 5H 5)( c-C 8H 11)(PR 3) (R = Me, Et) are reported, together with a structural study of the PEt 3 complex. As with other low valent half-open zirconocenes, the...
The reaction of Zr(C 5H 5)Cl 2Br with 3 equiv. of the 6,6-dimethylcyclohexadienyl anion (6,6-dmch −) in the presence of 2 equiv. of PMe 3 leads to the edge-bridged half-open zirconocene complex, Zr(C 5H 5)(6,6-dmch)(PMe 3) 2, an analogue of which has been ...
Liu P,Feng X J,He R.Salen and half-salen palladium (II)complexes:synthesis,characteriztion and catalyticactivity toward Suzuki-Miyaura reaction. Tetrahedron . 2010Liu, P.; Feng, X. J.; He, R. Salen and half- salen palladium(II) complexes: synthesis, characterization and catalytic activity ...