The equilibrium constant of the reaction AuCl 4 − + 2Au + 2Cl − = 3AuCl 2 − has been determined directly by analyzing, spectrophotometrically, equilibrium mixtures prepared from both the AuCl 4 − side and the AuCl 2 − side. From extrapolation of the formal equilibrium ...
Thus the lack of voltage control in the dendrites did not create dramatic differences in the rate of inactivation at various parts of the cell. If the inactivation time constant decreased substantially with depolarization beyond the half-inactivation voltage, the steady-state activation and inactiva...
Generally, the reaction was faster for the RhCp* complexes than for the Ru(p-cym) analogs. The 8-hydroxyquinoline complexes showed the fastest reaction in both cases. The [Ru(p-cym)(en/phen)(H2O)]2+ complexes reached chemical equilibrium within only hours, while the reaction between 1-...