The stability constants for the formation of the [RhCp*(N,N/O)(N)]2+/+ and [Ru(p-cym)(N,N/O)(N)]2+/+ complexes in the reaction between the [RhCp*(N,N/O)(H2O]2+/+ and the monodentate ligands showed the following trends: (i) at pH 7.4, the formation constants were ...
The full Heusler phase can be in-situ formed via following reaction: Zr0.25Hf0.75NiSn + 0.02Ni → 0.98Zr0.25Hf0.75NiSn (HH) + 0.02Zr0.25Hf0.75Ni2Sn (FH) Due to the immiscibility of the HH phase Zr0.25Hf0.75NiSn and FH phase Zr0.25Hf0.75Ni2Sn, and the similarity of their crystal ...