3 Experience to date10 indicates that Equation (6) is valid for small ΔE0, but fails for ΔE0 > 500 mV even if the pressure dependence of f is taken into account. Electrochemical studies of bioinorganic redox reagents are complicated by the tendency of metalloproteins to adsorb irreversibly...
The DNA binding constant (Kb) of the compounds with CT-DNA was determined by UV-vis through the Benesi–Hildebrand equation, namely from the ratio of the y-intercept to the slope in the plots A0/A−A0 vs. 1/[DNA] [36]. The found Kb values were similar for DACHPtCl2 and oxaliplati...
pKa values of the complexes were calculated using Origin 2018 by plotting the absorbance at the corresponding wavelength against the pH and fitting it to the Boltzmann equation to obtain the inflection point. For complexes 2–4, the pKa values were calculated to be around 10 (Materials and ...