对Gouy-Chapman模型的思考 Gouy-Chapman model 假设 GC他们还对模型作了定量的处理,提出了如下四点假设; ① 假设表面是一个无限大的平面,表面上电荷是均匀分布的。 ② 扩散层中,正、负离子都可视为按Boltzmanm分布的点电荷。 ③ 介质是通过介电常数影响双电层的,且它的介电常数各处相同。 ④ 假设分散系统中...
贾景超;杨庆.Gouy-Chapman双电层模型在蒙脱石长程膨胀中应用.大连理工大学学报.2010.239-244贾景超, 杨庆. Gouy-Chapman 双电层模型在蒙脱石长 程膨胀中应用[J]. 大连理工大学学报, 2010, 50(2): 239 -244. JIA Jing-chao, YANG Qing. Application of Gouy- Chapman double layer model to long-range ...
(2)离子的电子层数越多,离子极化越强烈,离子的有效电荷增加越多. 关键词: Hofmeister效应; 动态光散射; 凝聚动力学; 有效电荷系数; 电场; 非经典极化效应 中图分类号: O646; O648 Quantitative Characterization of Specific Ion Effects Using an Effective Charge Number Based on the Gouy-Chapman Model GAO ...
Calculations based on the Gouy-Chapman model yield the electrical terms. The remainder in the equilibrium equations gives the nonelectrical, standard-state free energy changes. The degree of consistency between the integral and the differential results shows that the Gouy-Chapman model is not ...
Semiclassical model of electron transfer at electrocatalytic interfaces 1433 02:01:00 Debye-Huckel理论Ⅰ 1042 44:00 Debye-Huckel理论Ⅱ 742 34:00 界面热力学 1465 02:21:00 电极界面热力学应用 硫酸在铂单晶上的电化学吸附 1506 01:06:00 电极溶液界面的热力学总结 1473 30:00 Gouy-Chapman理论Ⅱ 137...
The size of the ions and the possibility of their interaction with the charges on the surface of the particles have been neglected. A finite ion size, though, would limit the distance between them and the particle. Stern modified the Gouy-Chapman model by introducing a layer of thickness,δ...
JIA Jing-chao, YANG Qing. Application of Gouy- Chapman double layer model to long-range swelling of montmorillonite[J]. Journal of Dalian University of Technology, 2010, 50(2): 239-244.Gouy-Chapman双电层模型在蒙脱石长程膨胀中应用[J]. 贾景超,杨庆.大连理工大学学报. 2010(02)...
E.; May, S., Ionization properties of mixed lipid membranes: A Gouy-Chapman model of the electrostatic-hydrogen bond switch. Bba- Biomembranes 2011, 1808 (8), 1985-1992.D.H. Mengistu, E.E. Kooijman, S. May, Ionization properties of mixed lipid mem- branes: a Gouy-Chapman model of ...
May, Ionization properties of mixed lipid mem- branes: a Gouy-Chapman model of the electrostatic-hydrogen bond switch, Biochim. Biophys. Acta Biomembr. 1808 (2011) 1985-1992.Mengistu, D. H.; Kooijman, E. E.; May, S., Ionization properties of mixed lipid membranes: A Gouy-Chapman model...
Acta Phys.-Chim. Sin. 2014; 30 (12), 2272-2282.Gao XD, Li H, Tian R, Liu XM, Zhu HL. Quantitative characterization of specific ion effects using an effective charge number based on the gouy-chapman model . Acta Phys.-Chim. Sin. 2014; 30 ( 12 ), 2272–2282....