编译自:Name Reactions (A Collection of Detailed Reaction Mechanisms), Jie Jack Li, Gomberg–Bachmann reaction,page 267-268.
Gomberg–Bachmann反应 碱催化下芳基重氮盐和芳烃进行自由基偶联得到二芳基化合物的反应。 反应机理 反应实例 参考文献 1. Gomberg, M.; Bachmann, W. E. J. Am. Chem. Soc. 1924, 46, 2339. Moses Gomberg (18661947) was born in Elizabetgrad, Russia. He discover...
Gomberg reaction 冈伯格反应 Hey reaction 【化】 黑氏合成法 hey presto int. 突然地;立即(魔术师用语)您看,变! hey jude 是披头士乐队成员保罗·麦卡特尼创作的一首歌,字面意思是“嘿,茱蒂”。 Hey's hernia 包绕性腹股沟疝 Bachmann's bundle 【医】 巴克曼氏束(心耳间横肌束) Hey's ligaments...
[4]Bachmann,HoffmanninOrganicReactions,Vol.2,p224(NewYork,1944) [5]Hey,Dermer,Edmison,Chem.Revs.,57,83(1957) [6]Augood,Williams,ibid.,57,129(1957) [7]Reactionmechanism:Ruchardt,Merz,TetrahedronLetters,1964(36),2431 [8]Ruchardt,Freudenberg,ibid.1964(48),3623 [9]Eliel,Saha,J.Org.Chem....
M. Gomberg, W. E. Bachmann, J. Am. Chem. Soc. 46, 2339 (1924). Alkali dependent formation of diaryl compounds from aryl diazonium salts and aromatic compounds.W. E. Bachmann, R. A. Hoffman, Org. React. 2, 224 (1944); O. C. Dermer, M. T. Edmison, Chem. Rev. 57, 77 (...
The synthesis of diaryls (mostly unsymmetrical diaryls) by condensation of aryl diazonium salts with aromatic or heterocyclic compounds in the presence of aqueous NaOH is referred to as the Gomberg鈥揃achmann alkaline reaction. It is known that this reaction is rapid and easy to carry out, ...
Acknowledgment.-This workwassupportedby NationalInstitutesofHealthGrantGM-08848. Theresiduedistilledat100-112 TheGomberg-BachmannReaction withBenzene-d ERNESTL.ELIEL ANDJADUG.Sma DepartmentofChemistryandRadiationLaboratory,' UniversityofNotreDame,NotreDame,Indiana ANDSEYMOUR MEYERSON ResearchandDevelopmentDepartment...
Dinitrobiphenyls Obtained by the Gomberg-Bachmann Reaction: A Quantitative Study1 The Gomberg-Bachmann reaction of 3-nitrobenzenediazonium chloride with nitrobenzene and sodium acetate gives 3,X′-dinitrobiphenyls (and tar). The ratio of isomers produced 3,2′ :3,3′:3,4′ is 31:25:44. ...
5) Hershberg reaction 赫什伯格反应6) gomberg condensation 冈伯格联芳基反应补充资料:冈伯格-巴赫曼-埃反应 分子式:CAS号:性质:芳香族重氮盐与液态芳烃混合,滴加入过量的氢氧化钠水溶液,发生偶联反应。这是合成不对称芳烃偶联产物的重要方法。收率通常在20%～70%。用于分子内的芳环偶联,收率更高。 说明:补充...
Gomberg-Bachmann-Hey reaction 英文Gomberg-Bachmann-Hey reaction 中文【建】 冈伯格-巴赫曼-海伊反应