In the final sections, the use of glyme-based electrolytes in high-energy cells arranged by coupling a lithium-metal anode with conventional insertion cathodes as well as in alternative and new batteries exploiting the Li鈥揝 and Li鈥揙2 conversion processes is described in detail. The various ...
Localized high-salt-concentration electrolytes each containing a salt, a glyme as a solvent, and a fluorinated diluent. In some embodiments, the glyme has a chemical formula R—(O—CH—CH)—O—R, wherein n=1 to 4 and at least one of Rand Ris a hydrocarbon sidechain having at least 2...
Glyme-Based Nonaqueous Electrolytes for Rechargeable Lithium Cells. Electrochim. Acta 2004, 49, 979-987.Tobishima, S.; Morimoto, H.; Aoki, M.; Saito, Y.; Inose, T.; Fukumoto, T.; Kuryu, T. Glyme-based nonaqueous electrolytes for rechargeable lithium cells. Electrochim. Acta 2004, 49,...
On the other hand, the later aspect was examined with Li | Li symmetric cells containing the glyme-based electrolytes. As a result, the LiN(SO_2CF_3)_2/G4 having a higher supplying rate, i.e. σ, owing to its higher α_(app) exhibited an excellent Li deposition/dissolution and Li...
Herein, we focused on the impact of the Li ion transport properties in oligoether (glyme)‐based electrolytes on the deposition/dissolution efficiency of Li metal anodes. Analysis of the low‐frequency impedance spectra of Li‐plated Cu/Li cells revealed that the diffusion resistan...
This study demonstrates that the amount of discharge product (Li2O2) precipitated on the separator in a lithium oxygen cell using glyme-based electrolytes depends on the anion. The stability of the discharge intermediate (LiO2) in the electrolyte has been shown to depend on the anionic species,...
In this chapter, general properties and recent studies of glyme-based electrolytes for non-aqueous lithium–air batteries (LABs) will be introduced and discussed together with and through our research...doi:10.1007/978-981-33-6668-8_40Morihiro Saito...
Localized high-salt-concentration electrolytes each containing a salt, a glyme as a solvent, and a fluorinated diluent. In some embodiments, the glyme has a chemical formula R—(O—CH—CH)—O—R, wherein n=1 to 4 and at least one of Rand Ris a hydrocarbon sidechain having at least 2...
Rechargeable batteries composed of metallic Mg negative electrode, glyme-based electrolytes and organic positive electrode (2,5-dimethoxy-1,4-benzoquinone (DMBQ)) were proposed. The charge-discharge performance of the batteries was investigated at 30掳C. The discharge capacity reaches ca. 200 mAh g...
Systematic Investigation on Ion Transport Mechanism in Glyme-Based Electrolytes for Li-Air Batteriesdoi:10.1149/ma2016-02/5/794S. YamadaY. TachikawaK. ItoY. KuboM. Saito