In the final sections, the use of glyme-based electrolytes in high-energy cells arranged by coupling a lithium-metal anode with conventional insertion cathodes as well as in alternative and new batteries exploiting the Li鈥揝 and Li鈥揙2 conversion processes is described in detail. The various ...
Highly concentrated glyme‐based electrolytes are friendly to a series of negative electrodes for potassium‐based batteries, including potassium metal. However, their compatibility with positive electrodes has been rarely explored. In this work, the influence of the molar fraction of potassium bis(tri...
electrolytesinterfaceslithiumsolid electrolyte interphaseThe formation of a stable solid electrolyte interphase (SEI) is a prerogative for functional lithium metal batteries. Herein, the formation and evolution of such SEI in contact with glyme‐based electrolytes is investigated under open circuit voltage ...
The determination of stable Al-Cl-glyme complex structures by density functional theory (DFT) calculations enables the modeling for molecular dynamics (MD) simulations of the bulk electrolytes, namely aluminum chloride (AlCl _3 )-diglyme (G2)-cosolvent system. It is shown that a tridentate ...
Solvate ionic liquids (SILs), comprising long-lived, Li solvate cations and counter anions, serve as highly Li-ion-conductive and non-flammable electrolytes for use in lithium secondary batteries. In this work, we synthesized a series of novel redox-active glyme(oligoether)-Li salt-based SILs,...
These electrolytes were assembled into Li-O-2 batteries and the voltage and capacity data were recorded during cycling discharge/charge test. The effects of organic electrolyte physical properties on the battery impedance and cyclic life were discussed. Among the eight electrolytes, lithium bis(tri...
Electrolytes providing a high capacity (up to 400 mA h g?1) of an organic anode material, which is based on a polymeric product of a condensation of triquinoyl with an aromatic amine, in a lithium half-cell have been developed and studied. A complex study of a 1 M solution of LiPF6...
Herein, we focused on the impact of the Li ion transport properties in oligoether (glyme)‐based electrolytes on the deposition/dissolution efficiency of Li metal anodes. Analysis of the low‐frequency impedance spectra of Li‐plated Cu/Li cells revealed that the diffusion resistance of...
In this chapter, general properties and recent studies of glyme-based electrolytes for non-aqueous lithium–air batteries (LABs) will be introduced and discussed together with and through our research...doi:10.1007/978-981-33-6668-8_40Morihiro Saito...
On the other hand, the later aspect was examined with Li | Li symmetric cells containing the glyme-based electrolytes. As a result, the LiN(SO_2CF_3)_2/G4 having a higher supplying rate, i.e. σ, owing to its higher α_(app) exhibited an excellent Li deposition/dissolution and Li...