a certain type ofglycosidic bondscan affect the water solubility ofpolysaccharidesdue to the variation in their symmetrical structure that facilitates the intermolecular association between the chains (Fig. 7c) [120]. As a matter of fact,antioxidant activityrelies on the position and quantity ofhydrox...
Anomeric memory of the glycosidic bond upon fragmentation A closer examination of the galactose C fragment reveals that its fingerprint is not exactly identical to that of the galactose standard shown in Fig. 1a. Indeed, the small band at 3605 cm−1 present in the spectrum of the standard...
This leads us to ask: does a simpler, more direct reaction pathway exists which allows for the one-pot synthesis of nucleosides via formation of the β-glycosidic bond between separately preformed sugar and nucleobase moieties? The same question was asked by Orgel and collaborators more than 40 ...