Gatterman‐Koch reactioncatalystaluminum chlorideFormylation of arenes using carbon monoxide and hydrogen chloride in the presence of aluminum chloride under high pressure.doi:10.1002/0471264180.or005.06Nathan N. CrounseThe Hilton-Davis Chemical Company...
The scope of the Gattermann-Koch reaction is limited due to the lack of suitable substrates, as it is mostly restricted to alkylbenzenes; so Gattermann introduced a modification which allowed the formylation of phenols, phenolic ethers, an...
性质:又称加特曼甲酰化反应(Gattermann formylation reaction)。芳香族化合物在三氯化铝(或氯化锌等路易斯酸)催化下与氰化氢和氯化氢共热,生成加合物经水解,产生甲酰化产物。常用的溶剂有乙醚、苯、氯苯、氯代烷。通常的芳烃进行甲酰化产率较低,但合成酚和酚醚能收到很好的效果,是合成这类化合物常用的方法。主要...
aldehydes by the treatment of aromatic compounds with CO and HCl in the presence of AlCl 3 and cuprous chloride, by which CO and HCl behave like the hypothetical formyl chloride and react in a fashion similar to other acyl chlorides, is generally known as the Gattermann–Koch formylation. It...
Gattermann–Koch reactionFormylation of arenes using carbon monoxide and hydrogen chloride in the presence of aluminum chloride under high pressure.doi:10.1007/978-3-319-03979-4_117Alexander R. SurreySterling-Winthrop Research Institute, Rensselaer, New YorkName Reactions in Organic Chemistry...
Formylation of arenes using carbon monoxide and hydrogen chloride in the presence of aluminum chloride under high pressure.These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.Li, Jie Jack...
Gattermann–Koch reactionFormylation of arenes using carbon monoxide and hydrogen chloride in the presence of aluminum chloride under high pressure.doi:10.1007/978-3-642-01053-8_109LiJie JackSpringer Berlin Heidelberg
4) gattermann koch synthesis 伽特曼 柯区合成5) Grundmann aldehyde synthesis 格伦德曼醛合成法6) Gattermann amide synthesis 加特曼酰胺合成补充资料:加特曼甲酰化反应(Gattermann formylation reaction) 分子式:CAS号:性质:又称加特曼甲酰化反应(Gattermann formylation reaction)。芳香族化合物在三氯化铝(或氯化锌...
3) gattermann koch synthesis 伽特曼 柯区合成4) Grundmann aldehyde synthesis 格伦德曼醛合成法5) Gattermann reaction 伽特曼反应6) Gattermann-Skita synthesis 加特曼-吹田合成补充资料:加特曼甲酰化反应(Gattermann formylation reaction) 分子式:CAS号:性质:又称加特曼甲酰化反应(Gattermann formylation ...
性质:又称加特曼甲酰化反应(Gattermann formylation reaction)。芳香族化合物在三氯化铝(或氯化锌等路易斯酸)催化下与氰化氢和氯化氢共热,生成加合物经水解,产生甲酰化产物。常用的溶剂有乙醚、苯、氯苯、氯代烷。通常的芳烃进行甲酰化产率较低,但合成酚和酚醚能收到很好的效果,是合成这类化合物常用的方法。主要...