Functional group tolerance :是有机化工里的一个专用名词 意思是:官能团忍受性 官能团,是决定有机化合物的化学性质的原子或原子团。
FunctionalgrouptoleranceBTB-basedmetaleorganicframeworks(BTBbenzene-1,3,5-tribenzoate)StellaHeltenBasudevSahooPhilippMllerDanielJanen-MllerNicoleKleinRonnyGrnkerVolodymyrBonFrankGloriusStefanKaskelIrenaSenkovskaTechnischeUniversitDresden,InorganicChemistry,Bergstr.66,01062Dresden,GermanyWestfalischeWilhems-UniversitMnster,...
Suzuki–Miyaura reactions at 80 °C with a SPhos/Pd2(dba)3 catalyst system and a milder synthesis routine at 45 °C with a Pd-precatalyst system, that allows the coupling of corrole bromides with a wide range of boronic acid/ester derivatives and exhibits excellent functional group tolerance...