2. Meima, G. R.; Lee, G. S.; Garces, J. M. Friedel-Crafts Alkylation. In Friedel-Crafts Reaction Sheldon, R. A.; Bekkum, H., eds.; Wiley-VCH: New York. 2001, pp 550-556. (Review). 3. Bandini, M.; Melloni, A.; Umani-Ronchi, A. A...
This work has also been extended to alkylation with vinylchlorosilanes and (chloroalkyl)chlorosilanes. Substantial progress has been made in the development of the chemistry of this interesting class of organosilicon compounds. This review will describe the chemistry of the Friedel-Crafts alkylation of...
参考文献 一、Name Reactions (A Collection of Detailed Reaction Mechanisms), Jie Jack Li, Friedel–Crafts reaction,page 261-264. 二、Strategic Applications of Named Reactions in Organic Synthesis, László Kürti and BarbaraCzakó, Friedel-Crafts Alkylation. page 178-179. 相关反应 Friedel-Crafts酰基化...
金属铜催化不对称friedel-crafts alkylation reactions 铜催化不对称Friedel-Crafts烷基化反应是Friedel-Crafts反应的一种特殊形式,在有机合成中扮演了重要的角色。在反应中,铜作为催化剂,能够促进芳族烃或烷基卤化物与芳香族化合物之间发生取代反应,从而实现不对称烷基化。 这种反应可以通过使用手性诱导剂来获得立体异构体...
Heravi, M.M, Zadsirjan, V., Heydari, M., Masoumi, B., "Organocatalyzed Asymmetric Friedel‐Crafts Reactions: An Update", The Chemical Record, 2019, 19, 11, 2236-2340. Rueping, M., Nachtsheim, B. “A Review of New Developments in the Friedel–Crafts Alkylation – From Green Chemistry...
Friedel–Crafts alkylations are another important chain transfer reaction involving the electrophilic aromatic substitution of the solvent, the monomer, or the polymer with the elimination of a proton. From:Reference Module in Chemistry, Molecular Sciences and Chemical Engineering,2013 ...
The meaning of FRIEDEL-CRAFTS REACTION is a synthetic reaction in organic chemistry in which anhydrous aluminum chloride acts as the typical catalyst.
The Friedel-Crafts Alkylation represents one of the six classes of electrophilic aromatic substitution reactions. The diversity and scope of Friedel-Crafts Alkylations is broad.
o8.1FC(Friedel–Crafts)reactionsinorganicsyntheses Friedel–Craftsalkylation[edit] Friedel–Craftsalkylationinvolvesthealkylationofanaromaticringwithkyl halideusingastrongLewisacidcatalyst.[6]Withanhydrousferricchlorideas acatalyst,thealkylgroupattachesattheformersiteofthechlorideion.Thegeneral ...
Today: - Conclusion of Exp.1 “Kinetics” - Exp. 2, “Friedel-Crafts” Next time: MiniQuiz on Exps. 1 and 2! Calculations for..