The Friedel-Crafts Alkylation represents one of the six classes of electrophilic aromatic substitution reactions. The diversity and scope of Friedel-Crafts Alkylations is broad.
Friedel-CraftsAlkylation反应背景 •1877年，C.Friedel和J.M.Crafts用在苯中的薄铝条处理戊基氯，观察到苯戊基的结构。后来发现烷基氯与苯的反应很普遍，而且三氯化铝被确认是催化剂。以Lewis酸做催化剂，以各种烷基化试剂（烷基氯，烯烃，炔烃，醇）取代芳基和脂肪基的反应叫做Friedel-Crafts烷基化反应。反应通式 ...
一、Name Reactions (A Collection of Detailed Reaction Mechanisms), Jie Jack Li, Friedel–Crafts reaction,page 261-264. 二、Strategic Applications of Named Reactions in Organic Synthesis, László Kürti and BarbaraCzakó, Friedel-Crafts Alkylation. page 178-179. ...
Reaction of p-xylene with 1-bromopropane in the presence of aluminum trichloride (our lab experiment): Mechanism? Aluminum trichloride is a Lewis acid. What is a “Lewis acid”? What problems can arise during Friedel-Crafts alkylations? Suggest a procedure to get pure n-propyl product...
通过硒离子中间体进行的Friedel-Crafts烷基化反应示例 ReactIR有助于阐明机理 E Tang, Yinjiao Zhao, Wen Li, Weilin Wang, Meng Zhang, and Xin Dai, “Catalytic Selenium-Promoted Intermolecular Friedel−Crafts Alkylation with Simple Alkenes”, Org. Lett. 2016, 18, 5, 912-915. ...
求翻译:Friedel-Crafts Alkylation Reaction是什么意思?待解决 悬赏分:1 - 离问题结束还有 Friedel-Crafts Alkylation Reaction问题补充:匿名 2013-05-23 12:21:38 null 匿名 2013-05-23 12:23:18 Friedel-Crafts烷基化反应。 匿名 2013-05-23 12:24:58 Friedel工艺烷化反应 匿名 2013-05-23 12:...
乙烯酮的活化及其Friedel-Crafts酰基化反应制备芳香酮的DFT与实验研究 热度: Friedel–Craftsreaction Li_jiagen Outline • 一、Friedel-CraftsAlkylation • 1、Friedel-CraftsAlkylation应应应反背景 • 2、Friedel-CraftsAlkylation应应应反机理 •
The Friedel-Crafts alkylation reaction of benzene is illustrated below. A Lewis acid catalyst such as FeCl3or AlCl3is employed in this reaction in order to form a carbocation by facilitating the removal of the halide. The resulting carbocation undergoes a rearrangement before proceeding with the alky...
在无水三氯化铝等路易斯酸存在下，芳烃与卤烷作用，在芳环上发生亲电取代反应，其氢原子被烷基取代，生成烷基芳烃的反应，称为傅列德尔一克拉夫茨烷基化反应(Friedel-Crafts alkylation)；芳烃与酰卤或酸酐作用，芳环上的氢原子被酰基取代，生成芳酮的反应，称为傅列德尔～克拉夫茨酰基化反应(Friedel-Crafts acylation)...