N.: Rate constants for gas-phase reactions of the OH radical with a series of monoter- penes at 294 ± 1 K, Int. J. Chem. Kinet., 18, 287-299, 1986.Atkinson, R., Aschmann, S. M., and Pitts, J. N.: Rate constants for gas-phase reactions of the OH radical with a series ...
Rate constants for the gas-phase reactions of OH radicals with the C6−C14 2-methyl-1-alkenes and the C6−C10 trans-2-alkenes have been measured at 299 ± 2 K and atmospheric pressure of air using a relative rate technique. The rate constants obtained (in units of 10−11 cm3 molec...
Rate constants for the gas-phase reactions of ozone with unsaturated alcohols, esters, and carbonyls The kinetics of the gas-phase reaction of ozone with unsaturated alcohols, carbonyls, and esters in air have been investigated at atmospheric pressure, amb... D Grosjean,E Grosjean,II Edwin - 《...
gas phase disproportionation reactionFlash photolysis kinetic absorption spectroscopy was used to investigate the gas phase disproportionation reaction of CH 3O 2 radicals over the temperature range 228–380 K at pressures between 50 and 400 Torr of nitrogen diluent. The measured second order rate ...
6. For the irreversible gas-phase reaction: A 2B the following correlation was determined from laboratory data (the initial concentration of A is 0.2 g mol/L): 10° = 3.0 - mol For X 50.5: 10 For X > 0.5: -= 3.0+10(X -0.5) -1...
Gas-phase synthesis reactions We specialize in gas-phase reaction using proprietary catalysts, as well as our advanced R&D capabilities, to become a manufacturer specializing in gas-phase reactions driven by advanced technology. Schema 1 below is a typical use of a gas-phase reaction to produce ni...
Room-temperature rate constants for the gas-phase quenching of metastable molecular oxygen, O 2(a 1 Δ g) and O 2(b 1 Σ g+), by CO 2, N 2O, NO, NH 3, HCl and SO 2 The rate constants for collisional quenching of O 2(b 1Σ g +) by CO 2, N 2O, NO, NH 3, HCl ...
for the exothermic gas phase reactions at conditions suitable for the reaction; (d) removing a product stream comprising product and unreacted gases from the first reactor; (e) cooling and partially condensing the product stream to form a gas phase and a liquid phase; (f) separating the ...
Primary advantage of HFEs is their shorter lifetimes in the atmosphere due to the easiness of the decomposition by the reaction with OH radicals. It makes their global warming potentials (GWP) lower than the majority HFCs, which are also regarded as candidates for the replacement of CFCs and ...
For the reaction,Br2(g)+Cl2(g)2BrCl(g),recently used values for the equilibrium constant K° range from 6 to 10. The spread is due to the use (explicit or implicit) of different values for the dissociation energy of BrCl. The most recent assessment of this quantity yieldedDe=18247±...