The title compound, [Fe(CH)(CHNOS)], was synthesized from ferrocenecarboxylic acid and methyl 2-aminothiophene-3-carboxylate in modest yield. The substituted ring system is essentially planar through the amidothienylcarboxylate moiety, η-(CH)CONH(CHS)COMe, with the amido unit at an angle of ...
In attempts to grow single crystals of 3 in chloroform: hexane (ration 1:4 v/v) solvent mixtures under air at −18 °C, it was found that 3 further reacts with moisture and forms hydroxymethyl ferrocene (2) and 3,4-thiophenedicarboxylic anhydride (4) (Scheme 2). The structures of ...
Methyl 2‐(4‐ferrocenylbenzamido)thiophene‐3‐carboxylate and ethyl 2‐(4‐ferrocenylbenzamido)‐1,3‐thiazole‐4‐acetate, a unique ferrocene derivative containing a thiazole moietydoi:10.1107/S010827010501783XSteven AlleyJohn F. GallagherVincent M. Hooper...