In this study, the intermediate carbon structures containing iron during the graphitization process, obtained after the different steps of heat treatment from 200 to 1000 °C, were identified concerning the oxidation states of iron and morphological and structural variations. The role of iron in ...
ChemInform Abstract: Oxidation State-Dependent Light Sensitivity of a Ferrocene/ Dihydroazulene-Conjugate.doi:10.1002/chin.199125221organo-iron compoundsChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ...
It can be oxidized to [Cp2Fe]+, and the increase of the oxidation state of the iron atom makes the electrons of the locene ring (Cp) flow to the metal, which hinders the electrophilic substitution reaction of the ring. Ferrocene is resistant to hydrogenation and does not react with ...
(345° F). Chemically, ferrocene behaves likebenzeneand other aromaticcompoundsin that it undergoes substitution reactions. The removal of oneelectronfrom the molecule raises the iron atom to the next-higheroxidation state(i.e.,from +2 to +3), leading to the formation of salts containing the ...
Solid-state mechanochemical reactions of iron(II) chloride with cyclopentadienides of alkaline metals or thallium, which lead to the formation of ferrocene, were studied. The dependence of the yield of the product on the parameters of mechanical loading for the reaction with cyclopentadienylthallium ...
Ambi-valence taken literally: Ruthenium vs iron oxidation in (1,1′-diphosphinoferrocene)ruthenium(II) hydride and chloride complexes as deduced from spectroelectrochemistry of the heterodimetallic "mixed-valent" intermediates 2010, Organometallics The Coordination and Homogeneous Catalytic Chemistry of 1,...
1,2 In these propellants, several transition metal-based oxides, such as iron (Fe; III), cobalt (III), manganese (IV), and copper (Cu; II) oxides, and copper chromite are used as BRMs. Furthermore, various organometallic compounds of iron and copper also serve as BRMs.3, 4, 5, 6...
ferrocenium is the positive ion of ferrocene where iron is in the +1 oxidation state
These results may reveal the influence of the amide groups on suppressing the electronic interaction between the iron centers in my polymers. Thus, my systematic work on Fc-peptide conjugates lays solid foundations in the fields of structural control, biosensors, and material science. 展开 ...
W. Ferrocenium salts — the first antineoplastic iron compounds. Angew. Chem. Int. Ed. Engl. 23, 456–457 (1984). Article Google Scholar Neuse, E. W. & Kanzawa, F. Evaluation of the activity of some water-soluble ferrocene and ferricenium compounds against carcinoma of the lung by ...