CO2RR mechanisms lead to possible C1 products via two-, six-, and eight-electron pathways are systematically elucidated on Fe-N4porphyrin and Fe-N2S2porphyrin. Fe-N4porphyrin yields the most favorable product of HCOOH with a limiting potential of -0.70V. Fe-N2S2porphyrin exhibits low limiting ...
EES:轴向Fe-O配位的Fe1N4-O1活性位点助力宽电位范围内的高选择性CO2还原 清华大学彭卿教授,陈晨副教授,化学与精细化工广东省实验室Shoujie Liu报道了O掺杂的碳载体与Fe前驱体螯合,可以实现O原子与Fe中心的配位,并有效地将CO2RR转化为CO。 在将CO2电化学还原反应(CO2RR)转化为CO的过程中,CO在高法拉第效率(FECO)...