The latter underwent complexation with FeCl3 as an anionic NNN-pincer ligand coordinating the Fe(III) by one short Fe–N(s-triazine) and two equidistant Fe–N(pyrazole) bonds. The hexa- coordination environment was completed by two chloride ions and one methanol. The [Fe(BPT)Cl2(CH3OH)] ...
For the case of Hg2+ detection, HgCl2 solution was used instead of FeCl3. 3. Results 3.1. Spectral Properties of SQ The synthesis of sensor SQ was followed as reported literature [48] and the characterization for the compound was summarized in Figures S1–S3. The product was distinct from ...
Balouria, V.; Kumar, A.; Samanta, S.; Singha, A.; Debnath, A.K.; Mahajan, A.; Bedi, R.K.; Aswal, D.K.; Gupta, S.K. Temperature Dependent H2S and Cl2 Sensing Selectivity of Cr2O3 Thin Films. Sens. Actuators B 2013, 181, 471–478. [CrossRef] 14. Liu, Z.; Lv, B....
The resulting black suspension was ultrasonically mixed with PdCl2 (35 mg) ethanol solution (3 mL) for 1 h, then an ascorbic acid ethanol solution (8 mL) was dropped into the above mixture with vigorous stirring under 60 ◦C. After 2 h of reduction, the products were separated by a ...
Then, 2.7 g de FeCl3·6H2O was added and, once it was totally dissolved, 1.06 g of FeCl2·4H2O was added to the mixture. To synthesize this sample, N2 was bubbled through the solution during the precursor's addition to reduce the presence of oxygen as much as possible, which produces...