The molecules are monomeric with the yttrium being at the center of a distorted octahedron of chelate oxygen atoms (average Y-Ochelate = 2.28 (1) ) capped on one face by the water molecule (Y-Owater = 2.341 (3) ). The β-diketonate ligands wrap asymmetrically (two phenyl groups up, ...
Bond distances of both crystallographically independent molecules are almost identical, but there are some significant differences in bond angles (up to 60) and interplanar angles (up to 80). Each ruthenium atom exhibits a distorted octahedral envi...
J., A Cyclic Hexairon(III) Complex with an Octahedrally Coordinated Sodium Ion at the Center, an Example of the [12]Metallacrown-6 Structure Type. Angewandte Chemie International Edition in English 1995, 34 (4), 467-469.Caneschi, A,Cornia, A,Lippard, S. J.A Cyclic Hexairon(III) ...
Sakiyama, H., Tone, K., Yamasaki, M., Mikuriya, M.: Electronic spectrum and magnetic properties of a dinuclear nickel(II) complex with two nickel(II) ions ofC2-twisted octahedral geometry. Inorg. Chim. Acta. Mikuriya, M., Schumacher, M., Kawano, C., Akihara, T., Ono, K., Yoshio...
Each ruthenium atom exhibits a distorted octahedral environment formed by four oxygen atoms, two from each of the terminal and bridging acetylacetonate units, one γ-carbon of an adjacent acetylacetonate ligand, and the sulfur atom in the center of the complex. In agreement with the expected 3-...
Each tellurium atom also becomes six coordinated by weakly interacting with another sulfur atom of the dithiocarbamate ligand. The coordination environment around each tellurium is a very distorted octahedral constituted by two facial sets, one consisting of three carbon atoms and the other of three ...
The Re and M atoms exhibit somewhat distorted ReCI[sub4]O[sub2] and MO[sub6] octahedral surroundings, with the oxalate groups adopting the bis-bidentate bridging mode. Magnetic susceptibility measurements on polycrystalline samples of 1-5 in the temperature range 1.9-300 K show the occurrence ...
The resulting geometry for the CoN2O4 coordination environment can be described as distorted octahedral. Various hydrogen bonds of the type O-H···O and N-H···O are also present in the crystal structure. This arrangement leads to the formation of a 3D structure. A Rare Example of a ...
The structural analysis reveals that the dimeric complexes [Ni2(L)2(OAc)2] in cocrystal 3 and in compound 1 are almost identical-in both complexes, the Ni(II) ions possess a distorted octahedral geometry formed by the chelating tridentate ligand (L), a chelating acetate ion, and a ...
The cobalt(III) ion in the complex is six-coordinated with nitrogen atoms, three from Tp *, two from pyrazole and two from two thiocyanates, to form octahedral environment. The hydrogen atoms of O(2) of water molecule are connected by hydrogen bonds with S atoms of two adjacent complex ...