The First Example of Metallation of an Organogermanium Hydride with an Alkali Metal under Mild Conditions: Synthesis of 2,3,4,5-Tetraphenyl-1,1-bis(trimetylsilyl)-1-germa-2,4-cyclopentadiene - ResearchGatedoi:10.1007/BF00698525V. Ya. Lee...
The proposed mode of hydride transfer was inferred from GC analysis of the crude reaction product obtained for the synthesis of the compound 1a (RZH) from o-methylsulfanyl benzamide and benzaldehyde. GC analysis of the crude reaction product contained a peak with the same retention time as that...
. The options include LiFePO4, LiNiO2, and others. Selecting one of these options specifies some of the parameters in the "Temperature" tab. Currently there is not a preset battery for NMC type cells but you can specify these parameters in the "Temperature" tab bas...
Treatment of the fulvalene compound FvCr(2)(CO)(4)(PMe(2)Ph)(2)H-2 with 2 molar equiv of trityl radicals (Ph(3)C .) results in hydride hydrogen. atomion and formation of triphenylmethane and the new chromium-chromium-bonded dimer trans-FvCr(2)(CO)(4)(PMe(2)Ph)(2) (4). Ch...
aHowever, transition metal was needed in these reactions, because hydrous hydrazine as a hydride source firstly was decomposed to hydride intermediates that are common to those of the hydrogenation of unsaturated bonds with hydrogen. Furthermore, the scope of substrate is still limited, using ...
Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(<IMG src="http://www3.interscience.wiley.com/giflibrary/12b/eta.gif" border=0><SUP><FONT size=-1>5</FONT></SUP>-cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl-Hydride Exchange and an Example of ...
The structure is characterized by a roughly planar pentanuclear MoHgMn3 metal core consisting of a Hg-Mn3 triangulated rhomboidal framework with the Mo atom in plane ''spiked'' to the Hg atom. Although the hydride could not be located unambiguously, qualitative MO analysis indicates that it ...
The mechanism of these processes can be classified into: (a) Direct hydrogen-transfer or Meerwein–Ponndorf–Verley (MPV) reduction and (b) Hydridic route, with the formation of a metal-hydride species. The latter can be divided into both dihydridic and hydridic routes depending on the ...
The mechanism of these processes can be classified into: (a) Direct hydrogen-transfer or Meerwein–Ponndorf–Verley (MPV) reduction and (b) Hydridic route, with the formation of a metal-hydride species. The latter can be divided into both dihydridic and hydridic routes depending on the ...
At that in case of weak alcohols (CH3OH, TFE) there is also the additional interaction with the hydride ligand. These computational results allow explaining the observed experimental trends and give the first example of hydrogen bonding to a metal atom in the presence of hydride ligand....