When these closed-shell ions are subjected to CID, they commonly dissociate to daughter closed-shell ions and neutral fragments based on ‘even-electron rule’ [1]. It is rare that an electrospray ionization generated even-electron (EE) ion directly dissociates to form an odd-electron (OE) ...
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Each initial precursor cation is an even electron (EE) system and shows competing dissociations into both even (EE) and odd electron (OE) fragment ions. The latter reaction is a breach of the classic 'even-electron rule' in mass spectrometry. While the EE fragment dissociates similar to ...
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