N,N-Dimethylethylenediamine is a bidentate ligand that can be used: To synthesize Schiff base ligands to prepare their zinc alkyl and zinc alkoxide complexes that initiate ring-opening polymerization of lactides. As a ligand to prepare copper azido polymers. ...
No abstract is available for this article.doi:10.1002/chin.198009086ETCHEVERRY, S. B.BARAN, E. J.WILEY‐VCH Verlag GmbHCheminformEtcheverry SB, Baran EJ. Diphosphate as a bidentate ligand. Spectroscopic study of the bis(ethylenediamine)diphosphato- cobaltate(III) anion. Z Anorg Allg Chem. ...
the ligand acts asN,S-bidentate monodeprotonated and coordinates to ruthenium with the formation of a four-membered chelate ring, while in164, the thiosemicarbazone is doubly deprotonated and acts asO,N,S-tridentate ligand binding to ruthenium in a meridional fashion. Despite their different compo...
N,N,N',N'-Tetramethylethylenediamine (TEMED) is a bidentate tertiary amine Lewis base with excellent solvating properties. It is com.. What are the chemical properties of N,N,N',N'-Tetramethylethylenediamine?N,N,N',N'-Tetramethylethylenediamine is a flammable liquid that should be stored ...
The mixed-ligand saccharin complexes of Co, Ni and Cu with hydrazine and ethylenediamine have been prepared and characterized by elemental analyses, magnetic susceptibility and spectral methods. Hydrazine and ethylenediamine act as bidentate ligands through their N atoms, as expected. The metal ions ...
The ruthenium and osmium complexes [MCl2(diphosphane)(L)] (M=Ru, Os; L=bidentate amino ligand) and [MCl(CNN)(dppb)] (CNN=pincer ligand; dppb=1,4-bis- (diph... W Baratta,G Bossi,E Putignano,... - 《Chemistry》 被引量: 20发表: 2015年 Lithium Borohydride Ethylenediaminates:...
donated by the two Ethylenediamine ligands, the Ethylenediamine ligand being bidentate; forming two bonds to the metal per “en”. Because each “en” ligand in our Complex is bidentate, two different Isomers of our Complex are possible; a cis form and a trans form. These are pictured below...
The reaction of trans-(TMEDA)2VCl2 (TMEDA = N,N,N',N'-tetramethylethylenediamine) with both mono- and bidentate alkali-metal amides has been investigated. Utilization of 2 equiv of bidentate amide (N segment N)-M [M = Li, Na; N segment N... JJH Edema,G Sandro.,M Auke.,... -...
Two distinct types of host frameworks were constructed by cobalt chloride anion ([CoCl4]2− or [Co2Cl6]2−) and diprotonated N-bidentate ligand L1 (N,N,N′,N′-tetra-p-methylbenzyl-ethylenediamine) or chloride anion-directed L1. The pillared double - layered host framework constructed ...
In {[Cu(μ-HOr)(tmen)] · 1.5H 2O} n ( 2), the Cu(II) ion is coordinated by a tridentate orotate and one bidentate tmen ligand, and exhibits a square pyramidal geometry. These polymer chains are linked by hydrogen-bond interactions forming a three-dimensional network. Complex 2 ...