Hydrogen atoms, generated in a Wood's electric discharge tube, were allowed to react with tetrafluoroethene. The products of the reaction were found to be HF, CFH, CH, CFH, CFH, CFH, CH, and CHF. The formation of the products with the exception of HF was studied quantitatively from 30...
Methoxyethene (CAS NO.107-25-5) reacts vigorously with oxidizing materials. Explosive in the form of vapor when exposed to heat, flame or strong oxidizing agents. Reacts, possibly explosively with halogens (bromine, chlorine) or hydrogen halides (hydrogen bromide, hydrogen chloride) [Baker, ...
A vicinal ethylene bridged S/B frustrated Lewis pair (FLP) in situ generated by a hydroboration reaction of phenyl vinyl sulfide, reacts with p-tert-butylphenylacetylene by ethene/alkyne exchange and subsequent 1,2-addition of a second alkyne equivalent to give a zwitterionic sulfonium/borate pro...
Tetrachloroethylene can also react with bromine to form monobromo trichloro or dibromo dichloro compounds. Under the action of a catalyst, it can also react with hydrogen fluoride. In the presence of light, air and water for a long time, it slowly decomposes into trichloroacetaldehyde and ...
Reacts violently with mixtures of carbon tetrachloride and benzoyl peroxide; bromotrichloromethane; aluminum chloride and ozone. Incompatible with acids, halogens, nitrogen oxides; hydrogen bromide; aluminum chloride; chlorine dioxide; nitrogen dioxide. May accumulate static electrical charges, and may ...
Dissociatively adsorbed hydrogen forming ZrH and OH species on the ZrO2 did not react with gaseous ethene but was just replaced by it. However, preadsorbed π-bonded ethene was found to be hydrogenated by gaseous H2 to 'side-on' adsorbed ethane followed by a transformation into the more ...
C5Me5)2Sm(THF)2, 1, reacts with 1,2-bis(2-pyridyl)ethene to form [(C5Me5)2Sm]2(mu-eta2:eta2-pyCHCHpy), 2, in 80% yield if the reaction stoichiometry is 2.1. Combination of the same reagents in a 1:1 ratio forms [(C5Me5)2Sm]2[mu-eta3:eta3... EVANS,W. J,KEYER...
The catalytic performance and characterization of a durable perovskite-type chloro-oxide SrFeO3–δClσ catalyst selective for the oxidative dehydrogenatio... The catalytic performances and properties of SrFeO 3-0.190 and SrFeO 3-0.382 Cl 0.443 catalysts have been investigated for the oxidative dehy...
“organic” reactions. With the exception of the enzymatic ribonucleotide reduction, the results of the coenzyme B12-catalyzed enzymatic reactions formally correspond to isomerizations with vicinal exchange of a hydrogen atom and of a group with heavy atom centers. Homolytic cleavage of the (Co–C)...
The mechanism of action in organic synthesis involves the incorporation of 1-(4-Chlorophenyl)-2-nitroethene into the reaction mixture, where it reacts with other reagents to form the desired product. Storage ConditionsStore in a cool and dry place. View all ...