pH dependent catecholase activity of Fe(II) complexes of type [Fe(L)]X2 [L = N-(phenyl-pyridin-2-yl-methylene)-ethane-1,2-diamine; X = ClO4 (1), PF6 (2)]: Role of counter anion on turnover numberFe complexesCatecholase activity...
If a mixture of liquid ammonia and ethylene bromide is allowed to reach room temperature, an explosion may result with formation of ethylene diamine and higher homologs.Reaction between magnesium and 1,2-dibromoethane may become violent and release air-sensitive Grignard compounds.Reacts with hot ...
Synthesis of the title compound [5]: 3-ethyl-2- hydroxybenzaldehyde (1 g, 6.7 mmol) was dissolved in 30 mL of ethanol and (1R, 2R)-(−)-1,2-diphenylethane-1,2-diamine (0.71 g, 3.35 mmol) was added to the solution. The solution was heated to reflux for 4 h. The solvent was...
n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on...