KML, the ion-pair extraction constant of ML2+ with A−, and the adduct formation constant of MLA2 with L in benzene.Shoichi Katsuta and Fumiaki Tsuchiya and Yasuyuki TakedaTalantaKatsuta, S., Tsuchiya, F., Takeda, Y.: Equilibrium studies on complexation in water and solvent extraction of ...
Solubility and equilibrium constants of lead in carbonate solutions (25°C, I = 0.3 mol dm−3) The solubilities of PbCO3(s), 2PbCO2·Pb(OH)2(s), and of 3PbCO3 2Pb(OH)2(s) have been studied at 25°C ± 0.1°C in solutions of the constant ionic strengt... BP Schindler -...
- 《Journal of Chemical Physics》 被引量: 35发表: 1995年 Investigation of simple and water assisted tautomerism in a derivative of 1,3,4-oxadiazole: A DFT study that the tautomeric interconversion C to D has the lowest Gibbs free energy changes and so the highest equilibrium constant in the...
This chapter discusses the theory and practice of estimating equilibrium constants in immune systems. The simplest overall measure of the forces holding epitope and paratope together is the equilibrium constant. For practical measurement, at least one of the three components making up the equilibrium ...
whereβ−1 = kBT,kBbeing Boltzmann’s constant. The energy of the open linear conformation is the highest, averaging about 19 kJ/mol in the gas phase36. This is confirmed by our solution measurements, where this conformation is undetectable. In the limitβE0 ≫ 1 the stationa...
Fluctuations in the nanochemical reaction extent, which are found to be closely related to the stoichiometric coefficients, become more dominant for smaller systems and modify considerably the temperature dependence of the equilibrium constant. 展开 ...
All kinetic experiments were carried out at 25 °C under normal ambient pressures. A 2.0-g soil sample was placed in a 50-mL bottle containing 10-mL atrazine solution at a concentration of 30 mg L−1 and stirred using a constant temperature shaker. Samples were taken at set intervals and...
Specifically, we maintained a constant temperature difference while varying the duration of the preheating stage (indicated ast0in Fig.1c) to determine the quantity of liquid Se present in the precursor film. Furthermore, we compared the selenization processes involving solid-gas reactions with those...
where Γ∞ is the saturation adsorption, and aL is the Langmuir adsorption constant representing the concentration at which half of the interfacial coverage (at F = Γ∞ / 2) has been reached. The fitting of this isotherm to the experimental data gives values for the two characteristic paramete...
on the solubility of uranium(IV) dioxide, UO2(s) The equilibrium constant Kso, i.e., the solubility product for the reaction UO2(s) + 4H+ ← U4+ + 2H2O and the standard potential Eo for the redox equilibrium UO22+ + 2e ←UO2(s) have been determined at 25°C in 3 M NaClO4...