Reactions of the stearoylated enolic form of acetone, involving hexadecylketene as the reactive intermediateEnol esters, such as isopropenyl stearate, are useful intermediates capable of forming interesting derivatives of saturated aliphatic fatty acids. Under given conditions, whereas methyl stearate remains...
The results, presented in the form of center-of-mass velocity contour plots, suggest that a single dynamical mechanism is followed in the CID of enolic acetone cation as the collision energy is increased from 3.4 eV to 41 eV (CM). When interpreted according to the usual two-step model for...
Enolic acetone derivatives and process of making same from alpha mixture of acetone and its enolic formLOUGOVOY BORIS N.
Infrared spectra of pentafluoroprop-1-en-2-ol, the enol form of pentafluoroacetone, were recorded in the gaseous state and in argon and nitrogen matrices. Two different species, which interconverted upon warming, were found in the matrices. The Raman spectrum of the liquid alcohol was ...
increasing electron-attracting property of the substituent X in the aromatic 尾-ketoaldehydes ( 1 ), as well as increasing solvent basicity in the series propanediol-1, 2-carbonate, acetone < dimethylformamide < dimethylacetamide < pyridine, also shifts the equilibrium towards the trans -enol form....