Two novel organic–inorganic hybrid compounds, (H 2 enMe) 4 (H 3 O)[Ni(enMe) 2 ]·[Na 3 Mo 12 O 52 P 8 (OH) 10 ]·5H 2 O ( 1 ) and (H 2 enMe) 4 (H 3 O)[Cu(enMe) 2 ]·[Na 3 Mo 12 O 52 P 8 (OH) 10 ]·5H 2 O ( 2 ) (enMe=1,2-diaminopropane)...
Two novel inorganic-organic hybrid octamolybdate complexes [H(2)enMe](2)[MO8O26]center dot 2H(2)O 1 (enMe= 1,2-diaminopropane) and [Ni(2,2'-bpy)(3)](2)[delta-Mo8O26] 2 (2,2'-bpy=2,2'-bipyridine) have been hydrothermally synthesized and characterize...
Two novel inorganic–organic hybrid octamolybdate complexes [H 2enMe] 2[Mo 8O 26]·2H 2O 1 (enMe=1,2-diaminopropane) and [Ni(2,2′-bpy) 3] 2[δ-Mo 8O 26] 2 (2,2′-bpy=2,2′-bipyridine) have been hydrothermally synthesized and characterized by the elemental analyses, TG ...
A novel zinc-substituted polyoxovanadate, [{Zn(enMe)2}2(enMe)2{Zn2As8V12O40(H2O)}]·4H2O 1 (enMe = 1,2-diaminopropane), which is built up from Zn2As8V12O40(H2O) clusters and Zn(enMe)2 complexes, and further connected together by trans-enMe ligands, has been hydrothermally ...
A new polyoxotungstate formed by Wells–Dawson clusters and copper(II) complexes, [{Cu(enMe) 2 (H 2 O)}{Cu(enMe) 2 } 3 P 2 W 18 O 62 ]· n H 2 O (enMe=1,2-diaminopropane, n =0.81) has been synthesized under hydrothermal conditions. Single-crystal X-ray diffraction ...
A novel organic–inorganic hybrid material, [Cu(enMe)2(H2O)][{Cu(enMe)2}{Cu(enMe)2(H2O)W12O40(H2)}]·nH2O (n=0.33, enMe=1,2-diaminopropane), has been prepared under mild hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR and magnetic susceptibility ...