Electronic excitation of atomic ions provides numerous opportunities to observe dramatic effects in both the overall rates of reaction of such species and the distributions of products in these reactions. Three
Finally, for the real system, the effects of salt must be included in the consideration. In the following, we first address the bulk energy level offsets and then subsequently the other points. For the organic solvents, we find VB-HOMO offsets in the range 3–5 eV. Offsets of this ...
the ultrafast character and selectivity of the approach3. Ultrafast VC measurements would provide invaluable insights into important photophysical phenomena, such as electron–phonon-coupling effects, polaronic effects and ultrafast structural dynamics, which, in turn, may lead to improvements in material p...
Bistable electrochromic materials have been explored as a viable alternative to reduce energy consumption in display applications. However, the development of ideal bistable electrochromic displays (especially multicolour displays) remains challenging du
Although the discovery of opportunities is in its early stages, we discuss a few case studies in which the use of HEMs has led to improved material properties and device performance. We also correlate features with the respective properties and identify topics and effects for future investigations....
in absorption. Our calculations were carried out in the independent particle approximation96, and therefore phonon-assisted transitions and polaronic/excitonic effects were not considered. This analysis shows that the shoulder in the absorption spectrum of CuSbSe2arises because of its electronic structure...
Can This Coupling Enlarge the Knowledge of Gas-Phase Chemistry?Chapter 6. A Recent Development of the CS INDO Model: Treatment of Solvent Effects on Structures and Optical Properties of Organic Dyes; Chapter 7. Regioselectivity and Diastereoselectivity in the 1,3-Dipolar Cycloadditions of Nitrones ...
leading to the wafer bow and warp. The interaction between the intrinsic stress and the built-in stress in the GaN affected the electrical behavior of the device. The effects of the increased stress represent a significant reliability concern for the device, especially when considering the function...
Here we shall look at these effects in more detail, starting at the molecular level. We shall find that apart from the purely Coulombic interaction between two charges or permanent dipoles in a vacuum, all the other interactions are essentially polarization-type interactions. All atoms and ...
In fact, the electronegativity of the conjugated ligands is also very important because it could determine the ionic and covalent character of 2D c-MOFs due to the inductive effects. Covalent bonds are formed when the electronegativity of M and X are approximately equivalent, whereas ionic bonds ...