which leads to obvious differences on the electron localization functions (Fig.1b). As expected, the FePc/AB shows a symmetric charge distribution. Instead, strong electronic localization on the axial O atom accompanying with axial asymmetrical electronic distribution...
NBO/NLMO bonding analyses on Cp3U−ECp indicate that the bonding consists predominantly of a E→U σ-interaction arising from favorable overlap between the diffuse ligand lone pair and the primarily 7s/6d acceptor orbitals on U(III), with negligible U→E π-donation. The overall experimental ...
Forward-donation from the adsorbate to the substrate is significant, and there is also substantial back-donation, as reported in the literature for benzene on Pt and Ni surfaces. We found that the band of Pt 5dz2 orbitals plays an important role in the bonding between c-C5H5 and the ...
The p-electron donation from S atoms should make the metallacyclic planar. In fact, the five atoms of Ir(l), S(l), C ( l ) , C(2), S(2) are almost coplanar, the dihedral angle at the S(l)—S(2) vector being 176.8°. C(9I Fig. 1: Molecular structure of 1 Complex 2 ...
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2) if there is someone with a key fob jammer rigged up, then he can come up to you one dark night when you are about to get you in the car, and suggest a donation for turning the jammer off… I believe that the whole nice thing about these was you could unlock the car just bef...
Carbon nitrides can form coordination compounds or metallic oxides in the presence of transition metals, depending on the reaction conditions. By adjusting the pH to basic levels for mild synthesis with metals, composites like g-C3N4-M(OH)x (where M repr
Furthermore, companies use wording and labeling tactics such as “charitable donation” to dump their e-waste while profiting off of the “donation” [42]. This propagates the issue of environmental injustice and calls for prompt resolution. 5. COVID-19 Impacts It is well documented that the...
behavior, household surveys can be conducted to obtain primary data to understand citizens’ behavior towards WEEE, including meaningful aspects such as out-of-use storage, intention to repair damaged EEE, waste destination, place and time of acquisition, second-time acquisition, and donation [45]....
However, the strongly electron donating character of ddpd is incompatible with back-donation from a d8-cobalt(I) centre and consequently the [CoII/I(ddpd)2]2+/+ process becomes irreversible, likely caused by partial or full dissociation of ddpd. Inorganics 2018, 6, 86 17 of 37 The mer-...