By one-electron oxidation of the complexes, d9 copper(II)-radical ligand complexes are formed in gaseous state. Moreover, gas phase 3[Cu(L1)2]+ and 3[Cu(L2)2]+ complexes are more stable than the corresponding geometries with singlet spin configuration. The measured UV–Vis spectrum of [...
Development tests are normally conducted under “breadboard” conditions, in which subsystem performance is evaluated without a complete instrument configuration. Understanding the mission objectives, performance requirements, and expected conditions of use allows the manufacturer to develop an instrument that ...
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The stiff compromise between reliability and conductivity of copper interconnects used in sub-nanometer nodes has brought into focus the choice of encapsulation material. While reliability was the primary driver so far, herein, we investigate how electronic conductivity of Cu(111) thin films is influen...
Further theoretical calculation indicates that the adsorption of CuPc on a top site is the most favorable configuration, and the separation between the adsorbate and graphene is about 3.47. According to the density of states before and after CuPc adsorption, the LUMO of CuPc is slightly occupied...
Configuration of Electronic Component A configuration of an electronic component according to an exemplary embodiment is described below with reference to the drawings. FIG. 1 is an external perspective view of electronic components10and10ato10caccording to exemplary embodiments. FIG. 2 is an exploded ...
It is well known that the configuration of valence electrons is 2s 22p 2 for free C atom. The introduction of a carbon atom in iron clusters can undoubtedly change configuration of valence electrons. From Table 1, we find that the 2p state gains some amount of electrons. However, the 2s ...
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Due to strong electron–lattice coupling, a low (triclinic) lattice symmetry forms and produces the first-order Jahn–Teller (FOJT) distortion of the CuO6 octahedra and second-order Jahn–Teller (SOJT) distortion of the WO6 octahedra, which are caused by the 3d9 electron configuration of Cu2...
Orbital configuration of the valence electrons, ligand field symmetry, and manganese oxidation states of the photosynthetic water oxidizing complex. Analysis of the S2 state multiline EPR signals Inorg. Chem., 35 (1996), pp. 3307-3319 View in ScopusGoogle Scholar 64 M. Kusunoki A new paramagneti...