Smith D W.A new approach to the relationship between bond energy and electronegativity. Polyhedron . 2007Smith DW (2007) A new approach to the relationship between bond energy and electronegativity. Polyhedron 26:519–523 View ArticleSmith DW (2007) Polyhedron 26:519–523...
The dependence on and continuity of the energy and other molecular properties with respect to the number of electrons chemical reactivityIt was recently shown that the size consistency of the energy implies that, for any system with a rational number of electrons, the ... PW Ayers - 《Journal...
Electronegativity is a measure of the attraction of an atom for the electrons in a chemical bond. The higher the electronegativity of an atom, the greater itsattraction for bonding electrons. Ionization Energy Electronegativity is related toionization energy. Electrons with low ionization energies have ...
Based on the values, he proposed that the energy required to break a bond will be the average of bond energies of H2 (436 kJ/mol) and F2 (155 kJ/mol), i.e., 296 kJ/mol. However, the experimentally obtained bond energy of HF is 565 kJ/mol, which is much higher than the ...
An electronegativity scale for some transition metals may be constructed by means of the bond energy in halides together with a postulate concerning the arithmetic mean. The metal-metal bond energy is estimated at 40 kcal/mole on the bas~s of a comparison of numerous data regarding the homopolar...
A new electronegativity-based approach to the potential energy curve for diatomic molecules is proposed where the covalent binding is formulated in terms of the accumulation of electron density at the bond centre using the concepts of bond electronegativity and bond hardness while the ionic binding is...
Electronegativity and bond energy Recognition of quantitative relationships among atomic structure, electronegativity, nonpolar covalent radius, and homonuclear bond energy has permitted a ... Sanderson,T R. - 《Journal of the American Chemical Society》 被引量: 410发表: 1983年 New Scale of Atomic ...
Pauling, Linus. "The Nature of the Chemical Bond. IV. The Energy of Single Bonds and the Relative Electronegativity of Atoms". 1932, 54, 9, 3570-3582, J. Am. Chem. Soc., ACS Publications, September 1, 1932. Pauling, Linus. "The Nature of the Chemical Bond and the Structure of Mole...
He noticed that the bond energy E(AB) in a molecule AB is always greater than the mean of the bond energies E(AA) + E(BB) in the homonuclear species AA and BB. His argument was that in an "ideal" covalent bond E(AB) should equal this mean, and that the "excess" bond energy ...
^ Sanderson, R. T. (1983). "Electronegativity and bond energy." J. Am. Chem. Soc. 105:...