Starting with the building block calculations, we point out the participation of the CH3CS2- (dta) ligand in the mechanism of electron transfer. As the chain grows, the position and the geometry of the equatorial dta ligands are significantly altered. These changes indirectly control the PtI ...
Similar measurements were made on O2+, the species used to calibrate the apparatus geometry. A Maxwellian distribution of electron velocities was used with the measured cross sections to calculate rate constants, giving values extending to electron temperatures as high as 40,000°K. Comparison with...
Determine its electron geometry, the number of non-bonding domains on the central atom, and the polarity of the molecule. Draw the Lewis structure for SO2. Determine its electron geometry, the number of non-bonding domains on the c...
However, the presence of two metal-based chromophores interposed between the electron donor and acceptor subunits have never been explored. In principle this molecular arrangement, D-P-P-A, would allow to further separate the positive and negative charges, particularly when linear geometry is maintai...
Another example is the fabrication of mono- and bilayer ZnO coordinated in a trigonal-planar configuration in graphene nanopores [91]. In general, such nanopore-based fabrication is carried out under parallel electron beam irradiation with relatively low beam energy. However, the geometry and size ...