Acetonitrile (CH 3CN) has been studied by binary (e, 2e) spectroscopy at a total energy of 1200 eV in the symmetric non-coplanar geometry. The separation energy spectrum was determined at azimuthal angles of 0掳 and 8掳 in the energy range up to 40 eV. Above 23 eV the energy spectra...
Moreover, it was also found that the consistent approach (geometry and parameters obtained with the same theoretical method) strongly reduces the dependence of HOMA on the choice of the computational method and basis set used to optimize the geometry. In addition, the HOMA parameters for CC ...
Light absorption near a surface of conductive materials and nanostructures leads to the excitation of nonequilibrium, high-energy charge carriers: electrons above the Fermi level or holes below it. When remaining inside a material, these so-called hot carriers result in nonlinear, Kerr-type, optical...
Electron cyclotron resonance plasma deposition process and device for single-wall carbon nanotubes on a catalyst-free substrate, by injection of microwave power into a deposition chamber comprising a magnetic confinement structure with a magnetic mirror, and at least one electron cyclotron resonance area...
Electron paramagnetic resonance (EPR) spectroscopy has been extensively used for the determination of these metal ions without extensive disruption of the native protein moiety. It also detects variations in coordination geometry due to ligand substitutions as well as multiple valencies of the same ...
Starting with the building block calculations, we point out the participation of the CH3CS2- (dta) ligand in the mechanism of electron transfer. As the chain grows, the position and the geometry of the equatorial dta ligands are significantly altered. These changes indirectly control the PtI ...
The cobalt(III)-aryl amine complexes have been structurally refined by powder X-ray diffraction (PXRD) data as monoclinic unit cell with a distorted geometry. Cyclic voltammograms of the complexes exhibit CoIII/CoII and CoII/CoI reduction peaks with an indication of participation of electron ...
Metastability of C 3 H 5 2+ ions formed by electron impact ionization of propane was monitored with the help of a magnetic mass spectrometer of reversed geometry (BEE geometry). In the present paper, we report decay reactions resulting in C 3 H 4 + +H + , and C 3 H 3 + +H 2 ...
What is the electron pair geometry of H_2CO? Define electron affinity. In which corner of the periodic table is the highest? Explain why this is so. What is the electron domain of phosphorous trichloride? Why is electron affinity stronger (bigger negative) for Cl rather than Fl? What ion...
(MMMIII)-M-II-M-III double left right arrow(MMMIII)-M-III-M-II double left right arrow(MMMII)-M-III-M-III, which means that small external changes can have large structural effects, owing to the differences in coordination geometry between M2+ and M3+ sites (e. g., about 0.2 ...