Transition metal‐catalyzed cross‐coupling reaction between organometallic reagents and electrophiles is a potent method for constructing C(sp2)C(sp3) bonds. Given the characters of organometallic reagents, cross‐reductive coupling is emerging as an alternative strategy. The resurgence of...
Introduction Transition-metal-catalyzed direct C–H functionalizations open a new road for diverse C–C, C–P, and C–N bond construction in a one-step and atom economical way, without the requirement of prefunctionalized C–H coupling partners [1–6]. The cleavage of high energy C–H ...