Journal of Electroanalytical ChemistryCaix, C.; Chardon-Noblat, S.; Deronzier, A. Electrocatalytic reduction of CO2 into formate with [(η5-Me5C5)M(L)CI]+ complexes (L = 2,2 -bipyridine ligands; M = Rh(III) and Ir(III)). J. Electroanal. Chem. 1997, 434, 163-170. [CrossRef...
The electrochemical reduction of carbon dioxide (CO2) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while ...
Electrocatalytic reduction of CO2 into multicarbon (C2+) products is a highly attractive route for CO2 utilization; however, the yield of C2+ products remains low because of the limited C2+ selectivity at high CO2 conversion rates. Here we report a fluorine-modified copper catalyst that exhibit...
Electrocatalytic reduction of CO2 gas at Sn based gas diffusion electrodeCarbon dioxideTinElectroreductionFormateGas diffusion electrodeThe tin (Sn) based gas diffusion electrode was fabricated and applied for CO 2 electroreduction in a zero gap cell. The fabrication was done by electrodeposition from ...
using spectroelectrochemical monitoring, where photochemistry assists the cathodic activation of precursor complexes [Mn(CO)3(2,2使-bipyridine)Br] and [Mo(CO)4(6,6使-dimethyl2,2使-bipyridine)] to lower the catalytic overpotential needed to trigger the electrocatalytic reduction of CO2 to CO. ...
Electrocatalytic reduction of CO2 to either CO or formate ion in MeCN solution has been shown to occur using precursor complexes such as Ru(trpy)(dppene)Cl+ or cis-Rh(bpy)2(TFMS)2+[trpy = 2,2′,2″-terpyridine; dppene =cis-1,2-bis(diphenylphosphino)ethylene; bpy = 2,2′-bipyridi...
CO2reductionPhotoelectrocatalysisp–n heterojunctionCerium oxideCopper oxidePhotoelectrocatalytic reduction of CO2 to fuels has great potential for reducing anthropogenic CO2 emissions and also lessening our dependence on fossil fuel energy. Herein, we report the successful development of a novel photoelect...
Electrochemistry of aqueous pyridinium: exploration of a key aspect of electrocatalytic reduction of CO2 to methanol. Electrochemistry of aqueous pyridinium:Exploration of a key aspect of electrocatalytic reduction of CO2 to methanol. Yan Y,Zeitler E L,Gu J,et al. ... Y Yong,EL Zeitler,G ...
size effect has been regularly utilized to tune the catalytic activity and selectivity of metal nanoparticles (nps). yet, there is a lack of understanding of the size effect in the electrocatalytic reduction of co2, an important reaction that couples with intermittent renewable energy storage and...
The present study focused on the photoelectrocatalytic reduction of CO2 on CuBi2O4/TiO2㎞Ts(TiO2 nanotube arrays)catalyst under simulated solar irradiation. CuBi2O4 was successfully loaded on TiO2㎞Ts via pulse deposition regime from a nitric acid aqueous solution with Bi3+/Cu2+ molar ratio ...