This gives rise to the formation of the electric double layer (EDL) with a spaceヽharge layer that screens any externally applied voltage. The chapter calculates the energy of the EDL within the soヽalled Gouy〤hapman approximation for electrocapillarity and for all electrowetting (EW) experiments...
In electrochemical devices, such as batteries, traditional electric double layer (EDL) theory holds that cations in the cathode/electrolyte interface will be repelled during charging, leaving a large amount of free solvents. This promotes the continuous anodic decomposition of the electrolyte, leading ...
Fig. 4: Mechanism of liquid–solid CE and formation of electric double-layer. a The liquid contacts a virgin surface (before CE). b The water molecules and ions in the liquid impact the virgin surface and electron transfer between the water and the surface. c The surface is charged and ...
The assumptions for their theory are, among others. 1. The surface charge is continuous and uniform. 2. The ions in the solution are point charges. The electric potential in the double layer is given by the Poisson equation (Eq. 7.1): ...
网络双电层理论 网络释义 1. 双电层理论 ... ? 一、电极电位的产生 1889 Nernst双电层理论(theory of electric double layer): ? 将金属浸入其盐溶液中, 金属原子由于热 … wenku.baidu.com|基于2个网页
D., Boda D., J. Electroanal. Chem., 2005, Vol. 582, 16] for the charge profile of an electric double layer is used in conjunction with existing Monte Carlo data from the literature to assess the contact behavior of the electrode-ion distributions predicted by the density functional theory...
These theories fall into three categories: (1) the modified Poisson-Boltzmann equation (MPB) based on the Kirkwood-Loeb charging of an ion; (2) the adaption to the electric double layer of the Bogoliubov-Born-Green-Yvon (BBGY) hierarchy of integral equations; (3) the use of the Ornstein...
Effect of ionic size on the structure of spherical double layers: a Monte Carlo simulation and density functional theory study The effect of ionic size on the diffuse layer characteristics of a spherical double layer is studied using Monte Carlo simulation and density functional th... B Modak,CN...
Effect of Electro-Viscosity of Electric Double Layer on Lubricating Performance双电层电粘度对润滑性能的影响研究 The mathematical model was developed to account for the electro-viscosity function induced by electric double layer (EDL) in the light of EDL theory. The e... 白少先,黄平 - 《摩擦学学...
Fig. 4: Density-functional theory (DFT) calculations reveal the nucleation sites of Al adatom and dynamic nature of the electric double layers (EDLs). a Adsorption energy of Al on different hcp (H), fcc (F), and bridge (B) positions of Al/Ga interface compared with on pure Al and Ga...