而在文献中,又看到这样的说法:基于 El-Sayed rule,3LE-->1CT(局域激发三重态至电荷转移单重态之间的跃迁)或 3CT-->1LE 是被允许的。我的疑问是,(π,π*)单重态与1LE,或者,(n,π*)三重态与3CT,是一回事儿么?如果不是,其区别是什么呢?51 wzk老师您好。有一篇关于 El-Sayed rule 的
El-Sayed rulerate constantGreen functionOn the basis of a four-electronic-state model, the rate constant for intersystem crossing in aromatic compounds is formulated by means of a Green function technique. The rate constant is expressed as the sum of the four terms representing direct, indirect,...
From now through the primary ballot on August 7, everyone is locked in a tense waiting game to see if this progressive insurgency has real teeth, or if AOC will be the exception that proves the Democratic establishment rule. In short, people who are cheering El-Sayed on are less sure of...
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