近期,美国波士顿大学Amir H. Hoveyda教授课题组在Nature chemistry上,以“E- andZ-trisubstituted macrocyclic alkenes for natural product synthesis and skeletal editing”为题,发展了一种新型大环烯烃复分解(MRCM)策略,可以选择性合成E...
Nature Chemistry volume 14, pages 640–649 (2022)Cite this article 11k Accesses 29 Altmetric Metrics details Abstract Many therapeutic agents are macrocyclic trisubstituted alkenes but preparation of these structures is typically inefficient and non-selective. A possible solution would entail catalytic ...
陆展博士在J. Am. Chem. Soc.,Angew. Chem. Int. Ed.,Chem,Nature Communications等国际著名学术期刊上发表论文90余篇,被他引5000余次,撰写英文章节2章,获授权中国发明专利10余项;曾获国家优秀青年科学基金、Thieme Chemistry Jour...
E and Z alphα-C-galactosylceramidesby Juliα-Lythgoe-Kocienski chemistry: a test of the receptor-binding model for glycolipidimmunostimulants. Chen G,Chien M,Tsuji M, et al. ChemBioChem . 2006GUANGWU CHEN ET AL: " E and Z [alpha]-C-Galactosylceramides by Julia-Lythgoe-Kocienski Chemistry...
Catalytic cross-metathesis is a central transformation in chemistry, yet corresponding methods for the stereoselective generation of acyclic trisubstituted alkenes in either the E or the Z isomeric forms are not known. The key problems are a lack of chem
计算Z/E顺反异构的过渡态 使用方法：#opt=(calcall,ts,noeigentest,gdiis,notrustupdate,maxstep=5,...
Syntheses, structures, thermolyses of pentacoordinate 1,2-oxasiletanides ( 1 ), K + , 18-crown-6, {[&z.sbnd;C 6 H 4 &z.sbnd;C(CF 3 ) 2 O&z.sbnd;]SiPh[&z.sb... T Kawashima - 《Journal of Organometallic Chemistry》 被引量: 0发表: 2000年 ChemInform Abstract: Synthesis ...
I studied chemistry at the Wuhan University of Technology and Harbin Institute of Technology, where I received my BSc. and MSc. degrees, respectively. In 2021, I graduated from TU Dresden with a Ph.D. in theoretical chemistry. After that, I worked as a postdoc researcher at HZDR in Leipzi...
Cis vs Trans Isomers and E vs Z Isomers. What are they, what's the difference and when to use each case. This tutorial will give you a detailed understand of when and how to use each of these isomers in your organic chemistry course. From understanding g