Several functionalized biaryls and diarylmethanes containing the phloroglucinol subunit were synthesized in 55–85% yields using Negishi cross-couplings of 2,4,6-trimethoxyphenylzinc chloride with aryl and benzyl halides in the presence of catalytic quantities of Pd(DPEPhos)Cl. These simple to prepare...
Pd(DPEPhos)Cl2 Pd(DPEPhos)Cl2 规格: CAS: 205319-06-8 产品编号: HXWJ0000000365 MDL: MFCD09953446 品牌: Bellen 别名和识别编码 安全信息 药物反应 产品应用 相关文献及参考 Chemical NameDIchloro[bis(diphenylphosphinophenyl)ether]palladium(II)
源叶95% 英文名: Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) 别名: 双(二苯膦苯基)乙醚(II)二氯化钯;PdCl2(DPEphos); [bis(2-(diphenylphosphino)phenyl)ether]palladium(II) dichloride; dichloro(2,2-bis(diphenylphosphino)diphenyl ether)palladium(II); [bis(o-diphenylphosphinophenyl) eth ...
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Several functionalized biaryls and diarylmethanes containing the phloroglucinol subunit were synthesized in 55–85% yields using Negishi cross-couplings of 2,4,6-trimethoxyphenylzinc chloride with aryl and benzyl halides in the presence of catalytic quantities of Pd(DPEPhos)Cl. These simple to prepare...
USe of Incl_3 as a Cocatalyst and a Cl_2Pd(DPEphos)-P(2-Furyl)_3 Catalyst System for one-Pot Hydrometalation-Cross-Coupling and Carbometalation-cross-Coupling Tandem Process[J].Organic Letters,2004,(10):1531.doi:10.1021/ol049716f....
Pd(DPEPhos)Cl2-catalyzed Negishi cross-couplings for the formation of biaryl and diarylmethane phloroglucinol adductsdoi:10.1016/j.tet.2011.01.030Negishi cross-couplingBiarylsDiarylmethanesOrganozincPhloroglucinolCatechinSeveral functionalized biaryls and diarylmethanes containing the phloroglucinol subunit were ...