DMSO在酸性条件下的潜在爆炸风险尽管纯DMSO在室温下保持稳定，但当其处于酸性环境中时，情况则大不相同。在较低的温度下，DMSO就可能发生分解，且这种分解具有自催化的特性，可能导致失控甚至爆炸的情况出现。Nace和Monagle在研究亚砜与有机卤化物反应制备醛酮的过程中，观察到DMSO在反应条件下会分解生成低沸点产物，如...
前两周我们参考美国Corteva Agriscience公司(原陶氏杜邦农业事业部)杨强博士系统整理的题为Potential Safety Hazards Associated with Using N,N‑Dimethylformamide in Chemical Reactions的文章,对N,N-二甲基甲酰胺(DMF)与酸、碱、含卤化合物等不同类型的反应物大量混合时可能存在的安全隐患进行了详细的介绍。今天我们...
Barbara Czakó.Strategic Applications of Named Reactions in Organic Synthesis; Elsevier,2005.[7] Xiao...
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In the realm of organic synthesis, reagents can serve not only as solvents but also as synthons. Dimethyl sulfoxide (DMSO) is recognized for its efficiency in this dual capacity, enabling diverse chemical transformations. DMSO can generate various synthons, including methyl, methylene, methine, ...
ValuesofOrganicCompoundsinDMSO Xie,Kun*Qiao,ShuCheng,Cong (CollegeofChemistry&EnvironmentalEngineering,ChongqingThreeGorgesUniversity,Wanzhou,Chongqing404000) AbstractThequantitativestructure-propertyrelationship(QSPR)methodwasperformedtostudytherela- tionshipbetweenpKavaluesandelectrotopologicalstateindicesof45organiccompoun...
The Journal of Organic Chemistry 1998, 63 (12), 4016-4019. 2. Noda, A. et al. Optimum Measurement Conditions for Dimethyl Sulfoxide (DMSO) in Aqueous Solutions by Raman Spectroscopy. Journal of Solution Chemistry 2011, 40 (6), 1127-1143. 3. Durand, E. et al. Dimethyl Sulfoxide ...
What does DMSO mean in organic chemistry? What is DMSO in cell culture? What is DMSO used for in cell culture? Why is the tail of a phospholipid hydrophobic? Why is horse serum used in cell culture? Why are lipids nonpolar? Why are there unmyelinated neurons?
Since the 1860s the applications of DMSO have been widely described in the scientific literature. It was commonly used to dissolve organic agents in water for various different types of experimental purposes and named reactions in chemistry [4]. Soon thereafter, it was realized that DMSO had the...
Dimethyl sulfoxide is a commonly used solvent in many chemical reactions and is widely used in organic synthesis and industrial applications (polymer chemistry, pharmaceutical, and agricultural chemicals).