M.J. McGrath, I.F.W. Kuo, W.B.F. Ngouana, J.N. Ghogomu, C.J. Mundy, A.V. Marenich, C.J. Cramer, D.G. Truhlar, J.I. Siepmann, Calculation of the Gibbs free energy of solvation and dissociation of HCL in water via Monte Carlo simulations and continuum solvation models, ...
The very bad results obtained with PM3 (and also with AM1) are related to large errors in gas-phase proton affinity of water and gas-phase acidity of HCl. Indeed, estimation of p K a values shows that neither AM1 nor PM3 are able to predict HCl dissociation in liquid water since HCl...
New values of the dissociation constants of HCl° referring to low density supercritical solutions and near-critical temperatures of water (350–500°C and 500–2500 bars) have been obtained based on comparison of AgCl(s) solubility in NaCl or KCl solutions with Ag(s) solubility in HCl + NaC...
Electrolytic dissociation occurs when an electrolyte is dissolved in a polar solvent. For example, when hydrogen chloride, HCl, is dissolved in water to form hydrochloric acid, most of its molecules dissociate into hydrogen ions (H+) and chloride ions (Cl−). Some pure substances spontaneously ...
or the formation of higher-charged species fromcharged species. e.g. HCl(g) + aq → H⁺(aq) + Cl⁻(aq) dissociation(√) and ionization(√). It involves thebreaking of H-Cl bonds in HCl molecules (dissociation) to form H⁺(aq) and Cl⁻(aq) ...
Dissociation of HCl in Ethanol: Factors Affecting Ability In a textbook, HCl is said to remain as molecules in liquid ethanol. However, I still wonder whether HCl dissociates in ethanol to give H+ and Cl- ions. I think that as ethanol contains an OH group which is polar, ethanol molecu...
When acids undergo dissociation, they produce hydrogen ions. For example, consider the ionization of hydrochloric acid: HCl → H+(aq) + Cl-(aq) While some molecular compounds such as water and acids form electrolytic solutions, most dissociation reactions involve ionic compounds in water, or aque...
Intermolecular potential energy surface and spectra of He-HCl with generalization to other rare gas-hydrogen halide complexes A two-dimensional (rigid monomer) intermolecular potential energy surface (PES) of the He–HCl complex has been obtained fromab initiocalculations utilizin... G Murdachaew,K...
Using the example of HCl above, the addition of HCl to plasma will result in acidification. Similarly, the addition of lactate will also result in acidification. In contrast, the addition of the strong base Na+ in the absence of accompanying strong anion (as NaHCO3) will result in alkalin...
Elongation at the pointed ends of Limulus sperm actin bundles was to a smaller extent in the presence of 0.05 mM MgCl_2 than in its absence in 50mM KCl and 5mM Tris-HCl, pH8.0 at 25℃. This tendency was more evident in the presence of 4 ... K Maruyama,K Tsukagoshi,I Mabuchi - ...